Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(N,N-dimethyl­formamide-κO)nickel(II)

The title complex, [Ni(C(12)H(11)N(2)O(2))(2)(C(3)H(7)NO)(2)], lies on on an inversion center. The Ni(II) ion is coordinated in a slightly distorted octa­hedral coordination enviroment by four O atoms from two bis-chelating 4-acety-3-methyl-1-phenyl-1H-pyrazol-5-olate ligands in the equatorial plane...

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Detalles Bibliográficos
Autores principales: Zhu, Hualing, Wei, Zhen, Bu, Luxia, Xu, Xiaoping, Shi, Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007279/
https://www.ncbi.nlm.nih.gov/pubmed/21588145
http://dx.doi.org/10.1107/S1600536810026231
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author Zhu, Hualing
Wei, Zhen
Bu, Luxia
Xu, Xiaoping
Shi, Jun
author_facet Zhu, Hualing
Wei, Zhen
Bu, Luxia
Xu, Xiaoping
Shi, Jun
author_sort Zhu, Hualing
collection PubMed
description The title complex, [Ni(C(12)H(11)N(2)O(2))(2)(C(3)H(7)NO)(2)], lies on on an inversion center. The Ni(II) ion is coordinated in a slightly distorted octa­hedral coordination enviroment by four O atoms from two bis-chelating 4-acety-3-methyl-1-phenyl-1H-pyrazol-5-olate ligands in the equatorial plane and two O atoms from two N,N-dimethyl­formamide ligands in the axial sites. In the crystal structure, weak inter­molecular π–π stacking inter­actions with centroid–centroid distances of 3.7467 (13) Å link mol­ecules into chains extending alongthe b axis.
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spelling pubmed-30072792010-12-30 Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(N,N-dimethyl­formamide-κO)nickel(II) Zhu, Hualing Wei, Zhen Bu, Luxia Xu, Xiaoping Shi, Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ni(C(12)H(11)N(2)O(2))(2)(C(3)H(7)NO)(2)], lies on on an inversion center. The Ni(II) ion is coordinated in a slightly distorted octa­hedral coordination enviroment by four O atoms from two bis-chelating 4-acety-3-methyl-1-phenyl-1H-pyrazol-5-olate ligands in the equatorial plane and two O atoms from two N,N-dimethyl­formamide ligands in the axial sites. In the crystal structure, weak inter­molecular π–π stacking inter­actions with centroid–centroid distances of 3.7467 (13) Å link mol­ecules into chains extending alongthe b axis. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007279/ /pubmed/21588145 http://dx.doi.org/10.1107/S1600536810026231 Text en © Zhu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Hualing
Wei, Zhen
Bu, Luxia
Xu, Xiaoping
Shi, Jun
Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(N,N-dimethyl­formamide-κO)nickel(II)
title Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(N,N-dimethyl­formamide-κO)nickel(II)
title_full Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(N,N-dimethyl­formamide-κO)nickel(II)
title_fullStr Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(N,N-dimethyl­formamide-κO)nickel(II)
title_full_unstemmed Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(N,N-dimethyl­formamide-κO)nickel(II)
title_short Bis(4-acetyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′)bis­(N,N-dimethyl­formamide-κO)nickel(II)
title_sort bis(4-acetyl-3-methyl-1-phenyl-1h-pyrazol-5-olato-κ(2) o,o′)bis­(n,n-dimethyl­formamide-κo)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007279/
https://www.ncbi.nlm.nih.gov/pubmed/21588145
http://dx.doi.org/10.1107/S1600536810026231
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