Poly[diaqua­[3,5-bis­(trifluoro­meth­yl)pyrazolido]potassium]

The asymmetric unit of the title compound, [K(C(5)HF(6)N(2))(H(2)O)(2)](n), is composed of two 3,5-bis­(trifluoro­meth­yl)pyrazol­ide anions, two potassium cations and four water mol­ecules. The water mol­ecules and 3,5-bis­(trifluoro­meth­yl)pyrazolide anions act as bridges between the potassium ca...

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Detalles Bibliográficos
Autores principales: Phan, Hien Ngoc, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007281/
https://www.ncbi.nlm.nih.gov/pubmed/21588161
http://dx.doi.org/10.1107/S1600536810027133
Descripción
Sumario:The asymmetric unit of the title compound, [K(C(5)HF(6)N(2))(H(2)O)(2)](n), is composed of two 3,5-bis­(trifluoro­meth­yl)pyrazol­ide anions, two potassium cations and four water mol­ecules. The water mol­ecules and 3,5-bis­(trifluoro­meth­yl)pyrazolide anions act as bridges between the potassium cations. Each potassium cation is surrounded by four O atoms [K—O = 2.705 (3)–2.767 (3) Å] and four F atoms [K—F = 2.870 (7)–3.215 (13) Å]. The water mol­ecules and the 3,5-bis­(trifluoro­meth­yl)pyrazolide anions are connected by O—H⋯N hydrogen bonds, forming layers in the ab plane. All –CF(3) groups show rotational disorder between two orientations each.

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