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Poly[diaqua­[3,5-bis­(trifluoro­meth­yl)pyrazolido]potassium]

The asymmetric unit of the title compound, [K(C(5)HF(6)N(2))(H(2)O)(2)](n), is composed of two 3,5-bis­(trifluoro­meth­yl)pyrazol­ide anions, two potassium cations and four water mol­ecules. The water mol­ecules and 3,5-bis­(trifluoro­meth­yl)pyrazolide anions act as bridges between the potassium ca...

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Detalles Bibliográficos
Autores principales: Phan, Hien Ngoc, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007281/
https://www.ncbi.nlm.nih.gov/pubmed/21588161
http://dx.doi.org/10.1107/S1600536810027133
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author Phan, Hien Ngoc
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Phan, Hien Ngoc
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Phan, Hien Ngoc
collection PubMed
description The asymmetric unit of the title compound, [K(C(5)HF(6)N(2))(H(2)O)(2)](n), is composed of two 3,5-bis­(trifluoro­meth­yl)pyrazol­ide anions, two potassium cations and four water mol­ecules. The water mol­ecules and 3,5-bis­(trifluoro­meth­yl)pyrazolide anions act as bridges between the potassium cations. Each potassium cation is surrounded by four O atoms [K—O = 2.705 (3)–2.767 (3) Å] and four F atoms [K—F = 2.870 (7)–3.215 (13) Å]. The water mol­ecules and the 3,5-bis­(trifluoro­meth­yl)pyrazolide anions are connected by O—H⋯N hydrogen bonds, forming layers in the ab plane. All –CF(3) groups show rotational disorder between two orientations each.
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spelling pubmed-30072812010-12-30 Poly[diaqua­[3,5-bis­(trifluoro­meth­yl)pyrazolido]potassium] Phan, Hien Ngoc Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [K(C(5)HF(6)N(2))(H(2)O)(2)](n), is composed of two 3,5-bis­(trifluoro­meth­yl)pyrazol­ide anions, two potassium cations and four water mol­ecules. The water mol­ecules and 3,5-bis­(trifluoro­meth­yl)pyrazolide anions act as bridges between the potassium cations. Each potassium cation is surrounded by four O atoms [K—O = 2.705 (3)–2.767 (3) Å] and four F atoms [K—F = 2.870 (7)–3.215 (13) Å]. The water mol­ecules and the 3,5-bis­(trifluoro­meth­yl)pyrazolide anions are connected by O—H⋯N hydrogen bonds, forming layers in the ab plane. All –CF(3) groups show rotational disorder between two orientations each. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007281/ /pubmed/21588161 http://dx.doi.org/10.1107/S1600536810027133 Text en © Phan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Phan, Hien Ngoc
Lerner, Hans-Wolfram
Bolte, Michael
Poly[diaqua­[3,5-bis­(trifluoro­meth­yl)pyrazolido]potassium]
title Poly[diaqua­[3,5-bis­(trifluoro­meth­yl)pyrazolido]potassium]
title_full Poly[diaqua­[3,5-bis­(trifluoro­meth­yl)pyrazolido]potassium]
title_fullStr Poly[diaqua­[3,5-bis­(trifluoro­meth­yl)pyrazolido]potassium]
title_full_unstemmed Poly[diaqua­[3,5-bis­(trifluoro­meth­yl)pyrazolido]potassium]
title_short Poly[diaqua­[3,5-bis­(trifluoro­meth­yl)pyrazolido]potassium]
title_sort poly[diaqua­[3,5-bis­(trifluoro­meth­yl)pyrazolido]potassium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007281/
https://www.ncbi.nlm.nih.gov/pubmed/21588161
http://dx.doi.org/10.1107/S1600536810027133
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