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Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium]
The asymmetric unit of the title compound, [K(C(5)HF(6)N(2))(H(2)O)(2)](n), is composed of two 3,5-bis(trifluoromethyl)pyrazolide anions, two potassium cations and four water molecules. The water molecules and 3,5-bis(trifluoromethyl)pyrazolide anions act as bridges between the potassium ca...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007281/ https://www.ncbi.nlm.nih.gov/pubmed/21588161 http://dx.doi.org/10.1107/S1600536810027133 |
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author | Phan, Hien Ngoc Lerner, Hans-Wolfram Bolte, Michael |
author_facet | Phan, Hien Ngoc Lerner, Hans-Wolfram Bolte, Michael |
author_sort | Phan, Hien Ngoc |
collection | PubMed |
description | The asymmetric unit of the title compound, [K(C(5)HF(6)N(2))(H(2)O)(2)](n), is composed of two 3,5-bis(trifluoromethyl)pyrazolide anions, two potassium cations and four water molecules. The water molecules and 3,5-bis(trifluoromethyl)pyrazolide anions act as bridges between the potassium cations. Each potassium cation is surrounded by four O atoms [K—O = 2.705 (3)–2.767 (3) Å] and four F atoms [K—F = 2.870 (7)–3.215 (13) Å]. The water molecules and the 3,5-bis(trifluoromethyl)pyrazolide anions are connected by O—H⋯N hydrogen bonds, forming layers in the ab plane. All –CF(3) groups show rotational disorder between two orientations each. |
format | Text |
id | pubmed-3007281 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30072812010-12-30 Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium] Phan, Hien Ngoc Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [K(C(5)HF(6)N(2))(H(2)O)(2)](n), is composed of two 3,5-bis(trifluoromethyl)pyrazolide anions, two potassium cations and four water molecules. The water molecules and 3,5-bis(trifluoromethyl)pyrazolide anions act as bridges between the potassium cations. Each potassium cation is surrounded by four O atoms [K—O = 2.705 (3)–2.767 (3) Å] and four F atoms [K—F = 2.870 (7)–3.215 (13) Å]. The water molecules and the 3,5-bis(trifluoromethyl)pyrazolide anions are connected by O—H⋯N hydrogen bonds, forming layers in the ab plane. All –CF(3) groups show rotational disorder between two orientations each. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007281/ /pubmed/21588161 http://dx.doi.org/10.1107/S1600536810027133 Text en © Phan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Phan, Hien Ngoc Lerner, Hans-Wolfram Bolte, Michael Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium] |
title | Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium] |
title_full | Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium] |
title_fullStr | Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium] |
title_full_unstemmed | Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium] |
title_short | Poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium] |
title_sort | poly[diaqua[3,5-bis(trifluoromethyl)pyrazolido]potassium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007281/ https://www.ncbi.nlm.nih.gov/pubmed/21588161 http://dx.doi.org/10.1107/S1600536810027133 |
work_keys_str_mv | AT phanhienngoc polydiaqua35bistrifluoromethylpyrazolidopotassium AT lernerhanswolfram polydiaqua35bistrifluoromethylpyrazolidopotassium AT boltemichael polydiaqua35bistrifluoromethylpyrazolidopotassium |