(1R,2R)-N,N′-Bis(ferrocenylmeth­yl)-1,2-diphenyl­ethane-1,2-diamine

The title compound, [Fe(2)(C(5)H(5))(2)(C(26)H(26)N(2))], was synthesized from a chiral diamine and ferrocenecarboxaldehyde and subsequent reduction with NaBH(4). It has two chiral centers which both exhibit an R configuration. Two ferrocene groups are present in the mol­ecular structure, with their...

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Detalles Bibliográficos
Autores principales: Guo, Yi, Wang, Jianfeng, Zhang, Chixiao, Luo, Shuping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007283/
https://www.ncbi.nlm.nih.gov/pubmed/21588210
http://dx.doi.org/10.1107/S1600536810024293
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author Guo, Yi
Wang, Jianfeng
Zhang, Chixiao
Luo, Shuping
author_facet Guo, Yi
Wang, Jianfeng
Zhang, Chixiao
Luo, Shuping
author_sort Guo, Yi
collection PubMed
description The title compound, [Fe(2)(C(5)H(5))(2)(C(26)H(26)N(2))], was synthesized from a chiral diamine and ferrocenecarboxaldehyde and subsequent reduction with NaBH(4). It has two chiral centers which both exhibit an R configuration. Two ferrocene groups are present in the mol­ecular structure, with their cyclo­penta­dienyl ring planes showing an almost perpen­dicular arrangement [dihedral angle 88.6 (1)°].
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spelling pubmed-30072832010-12-30 (1R,2R)-N,N′-Bis(ferrocenylmeth­yl)-1,2-diphenyl­ethane-1,2-diamine Guo, Yi Wang, Jianfeng Zhang, Chixiao Luo, Shuping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(2)(C(5)H(5))(2)(C(26)H(26)N(2))], was synthesized from a chiral diamine and ferrocenecarboxaldehyde and subsequent reduction with NaBH(4). It has two chiral centers which both exhibit an R configuration. Two ferrocene groups are present in the mol­ecular structure, with their cyclo­penta­dienyl ring planes showing an almost perpen­dicular arrangement [dihedral angle 88.6 (1)°]. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007283/ /pubmed/21588210 http://dx.doi.org/10.1107/S1600536810024293 Text en © Guo et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Yi
Wang, Jianfeng
Zhang, Chixiao
Luo, Shuping
(1R,2R)-N,N′-Bis(ferrocenylmeth­yl)-1,2-diphenyl­ethane-1,2-diamine
title (1R,2R)-N,N′-Bis(ferrocenylmeth­yl)-1,2-diphenyl­ethane-1,2-diamine
title_full (1R,2R)-N,N′-Bis(ferrocenylmeth­yl)-1,2-diphenyl­ethane-1,2-diamine
title_fullStr (1R,2R)-N,N′-Bis(ferrocenylmeth­yl)-1,2-diphenyl­ethane-1,2-diamine
title_full_unstemmed (1R,2R)-N,N′-Bis(ferrocenylmeth­yl)-1,2-diphenyl­ethane-1,2-diamine
title_short (1R,2R)-N,N′-Bis(ferrocenylmeth­yl)-1,2-diphenyl­ethane-1,2-diamine
title_sort (1r,2r)-n,n′-bis(ferrocenylmeth­yl)-1,2-diphenyl­ethane-1,2-diamine
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007283/
https://www.ncbi.nlm.nih.gov/pubmed/21588210
http://dx.doi.org/10.1107/S1600536810024293
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AT zhangchixiao 1r2rnnbisferrocenylmethyl12diphenylethane12diamine
AT luoshuping 1r2rnnbisferrocenylmethyl12diphenylethane12diamine

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