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2-Amino-5-bromo­pyridinium 2-hy­droxy­benzoate

In the title compound, C(5)H(6)BrN(2) (+)·C(7)H(5)O(3) (−), the 2-amino-5-bromo­pyridinium cation and 2-hy­droxy­benzoate anion are essentially planar with maximum deviations of 0.020 (1) and 0.018 (2) Å, respectively. The anion is stabilized by an intra­molecular O—H⋯O hydrogen bond, which generate...

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Detalles Bibliográficos
Autores principales: Quah, Ching Kheng, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007284/
https://www.ncbi.nlm.nih.gov/pubmed/21588447
http://dx.doi.org/10.1107/S1600536810029855
Descripción
Sumario:In the title compound, C(5)H(6)BrN(2) (+)·C(7)H(5)O(3) (−), the 2-amino-5-bromo­pyridinium cation and 2-hy­droxy­benzoate anion are essentially planar with maximum deviations of 0.020 (1) and 0.018 (2) Å, respectively. The anion is stabilized by an intra­molecular O—H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, the cations and anions are linked by N—H⋯O hydrogen bonds into chains propagating along [010]. The chains contain R (2) (2)(8) ring motifs. The structure is further stabilized by π–π stacking inter­actions [centroid–centroid distances = 3.4908 (10) and 3.5927 (10) Å] and also features short Br⋯O contacts [2.9671 (13) Å].