Cargando…
2-Amino-5-bromopyridinium 2-hydroxybenzoate
In the title compound, C(5)H(6)BrN(2) (+)·C(7)H(5)O(3) (−), the 2-amino-5-bromopyridinium cation and 2-hydroxybenzoate anion are essentially planar with maximum deviations of 0.020 (1) and 0.018 (2) Å, respectively. The anion is stabilized by an intramolecular O—H⋯O hydrogen bond, which generate...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007284/ https://www.ncbi.nlm.nih.gov/pubmed/21588447 http://dx.doi.org/10.1107/S1600536810029855 |
Sumario: | In the title compound, C(5)H(6)BrN(2) (+)·C(7)H(5)O(3) (−), the 2-amino-5-bromopyridinium cation and 2-hydroxybenzoate anion are essentially planar with maximum deviations of 0.020 (1) and 0.018 (2) Å, respectively. The anion is stabilized by an intramolecular O—H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, the cations and anions are linked by N—H⋯O hydrogen bonds into chains propagating along [010]. The chains contain R (2) (2)(8) ring motifs. The structure is further stabilized by π–π stacking interactions [centroid–centroid distances = 3.4908 (10) and 3.5927 (10) Å] and also features short Br⋯O contacts [2.9671 (13) Å]. |
---|