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2-Amino-5-bromo­pyridinium 2-hy­droxy­benzoate

In the title compound, C(5)H(6)BrN(2) (+)·C(7)H(5)O(3) (−), the 2-amino-5-bromo­pyridinium cation and 2-hy­droxy­benzoate anion are essentially planar with maximum deviations of 0.020 (1) and 0.018 (2) Å, respectively. The anion is stabilized by an intra­molecular O—H⋯O hydrogen bond, which generate...

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Autores principales: Quah, Ching Kheng, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007284/
https://www.ncbi.nlm.nih.gov/pubmed/21588447
http://dx.doi.org/10.1107/S1600536810029855
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author Quah, Ching Kheng
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Quah, Ching Kheng
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Quah, Ching Kheng
collection PubMed
description In the title compound, C(5)H(6)BrN(2) (+)·C(7)H(5)O(3) (−), the 2-amino-5-bromo­pyridinium cation and 2-hy­droxy­benzoate anion are essentially planar with maximum deviations of 0.020 (1) and 0.018 (2) Å, respectively. The anion is stabilized by an intra­molecular O—H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, the cations and anions are linked by N—H⋯O hydrogen bonds into chains propagating along [010]. The chains contain R (2) (2)(8) ring motifs. The structure is further stabilized by π–π stacking inter­actions [centroid–centroid distances = 3.4908 (10) and 3.5927 (10) Å] and also features short Br⋯O contacts [2.9671 (13) Å].
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spelling pubmed-30072842010-12-30 2-Amino-5-bromo­pyridinium 2-hy­droxy­benzoate Quah, Ching Kheng Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(5)H(6)BrN(2) (+)·C(7)H(5)O(3) (−), the 2-amino-5-bromo­pyridinium cation and 2-hy­droxy­benzoate anion are essentially planar with maximum deviations of 0.020 (1) and 0.018 (2) Å, respectively. The anion is stabilized by an intra­molecular O—H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, the cations and anions are linked by N—H⋯O hydrogen bonds into chains propagating along [010]. The chains contain R (2) (2)(8) ring motifs. The structure is further stabilized by π–π stacking inter­actions [centroid–centroid distances = 3.4908 (10) and 3.5927 (10) Å] and also features short Br⋯O contacts [2.9671 (13) Å]. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007284/ /pubmed/21588447 http://dx.doi.org/10.1107/S1600536810029855 Text en © Quah et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Quah, Ching Kheng
Hemamalini, Madhukar
Fun, Hoong-Kun
2-Amino-5-bromo­pyridinium 2-hy­droxy­benzoate
title 2-Amino-5-bromo­pyridinium 2-hy­droxy­benzoate
title_full 2-Amino-5-bromo­pyridinium 2-hy­droxy­benzoate
title_fullStr 2-Amino-5-bromo­pyridinium 2-hy­droxy­benzoate
title_full_unstemmed 2-Amino-5-bromo­pyridinium 2-hy­droxy­benzoate
title_short 2-Amino-5-bromo­pyridinium 2-hy­droxy­benzoate
title_sort 2-amino-5-bromo­pyridinium 2-hy­droxy­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007284/
https://www.ncbi.nlm.nih.gov/pubmed/21588447
http://dx.doi.org/10.1107/S1600536810029855
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