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2-Amino-5-bromopyridinium 2-hydroxybenzoate
In the title compound, C(5)H(6)BrN(2) (+)·C(7)H(5)O(3) (−), the 2-amino-5-bromopyridinium cation and 2-hydroxybenzoate anion are essentially planar with maximum deviations of 0.020 (1) and 0.018 (2) Å, respectively. The anion is stabilized by an intramolecular O—H⋯O hydrogen bond, which generate...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007284/ https://www.ncbi.nlm.nih.gov/pubmed/21588447 http://dx.doi.org/10.1107/S1600536810029855 |
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author | Quah, Ching Kheng Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Quah, Ching Kheng Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Quah, Ching Kheng |
collection | PubMed |
description | In the title compound, C(5)H(6)BrN(2) (+)·C(7)H(5)O(3) (−), the 2-amino-5-bromopyridinium cation and 2-hydroxybenzoate anion are essentially planar with maximum deviations of 0.020 (1) and 0.018 (2) Å, respectively. The anion is stabilized by an intramolecular O—H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, the cations and anions are linked by N—H⋯O hydrogen bonds into chains propagating along [010]. The chains contain R (2) (2)(8) ring motifs. The structure is further stabilized by π–π stacking interactions [centroid–centroid distances = 3.4908 (10) and 3.5927 (10) Å] and also features short Br⋯O contacts [2.9671 (13) Å]. |
format | Text |
id | pubmed-3007284 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30072842010-12-30 2-Amino-5-bromopyridinium 2-hydroxybenzoate Quah, Ching Kheng Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(5)H(6)BrN(2) (+)·C(7)H(5)O(3) (−), the 2-amino-5-bromopyridinium cation and 2-hydroxybenzoate anion are essentially planar with maximum deviations of 0.020 (1) and 0.018 (2) Å, respectively. The anion is stabilized by an intramolecular O—H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, the cations and anions are linked by N—H⋯O hydrogen bonds into chains propagating along [010]. The chains contain R (2) (2)(8) ring motifs. The structure is further stabilized by π–π stacking interactions [centroid–centroid distances = 3.4908 (10) and 3.5927 (10) Å] and also features short Br⋯O contacts [2.9671 (13) Å]. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007284/ /pubmed/21588447 http://dx.doi.org/10.1107/S1600536810029855 Text en © Quah et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Quah, Ching Kheng Hemamalini, Madhukar Fun, Hoong-Kun 2-Amino-5-bromopyridinium 2-hydroxybenzoate |
title | 2-Amino-5-bromopyridinium 2-hydroxybenzoate |
title_full | 2-Amino-5-bromopyridinium 2-hydroxybenzoate |
title_fullStr | 2-Amino-5-bromopyridinium 2-hydroxybenzoate |
title_full_unstemmed | 2-Amino-5-bromopyridinium 2-hydroxybenzoate |
title_short | 2-Amino-5-bromopyridinium 2-hydroxybenzoate |
title_sort | 2-amino-5-bromopyridinium 2-hydroxybenzoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007284/ https://www.ncbi.nlm.nih.gov/pubmed/21588447 http://dx.doi.org/10.1107/S1600536810029855 |
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