Benzyl N-{(1S)-2-hy­droxy-1-[N′-(2-nitro­benzyl­idene)hydrazinylcarbon­yl]eth­yl}carbamate

The carbamate and hydrazone groups in the title compound, C(18)H(18)N(4)O(6), are approximately orthogonal [dihedral angle = 83.3 (4)°], and the carbonyl groups are effectively anti [O=C⋯C=O torsion angle = −116.2 (7)°]. The conformation about the imine bond [1.295 (11) Å] is E. The crystal packing...

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Detalles Bibliográficos
Autores principales: de Souza, Marcus V. N., Pinheiro, Alessandra C., Tiekink, Edward R. T., Wardell, Solange M. S. V., Wardell, James L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007287/
https://www.ncbi.nlm.nih.gov/pubmed/21588334
http://dx.doi.org/10.1107/S1600536810027273
Descripción
Sumario:The carbamate and hydrazone groups in the title compound, C(18)H(18)N(4)O(6), are approximately orthogonal [dihedral angle = 83.3 (4)°], and the carbonyl groups are effectively anti [O=C⋯C=O torsion angle = −116.2 (7)°]. The conformation about the imine bond [1.295 (11) Å] is E. The crystal packing is dominated by O—H⋯O and N—H⋯O hydrogen bonding, which leads to two-dimensional arrays in the ab plane.

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