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Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate
The carbamate and hydrazone groups in the title compound, C(18)H(18)N(4)O(6), are approximately orthogonal [dihedral angle = 83.3 (4)°], and the carbonyl groups are effectively anti [O=C⋯C=O torsion angle = −116.2 (7)°]. The conformation about the imine bond [1.295 (11) Å] is E. The crystal packing...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007287/ https://www.ncbi.nlm.nih.gov/pubmed/21588334 http://dx.doi.org/10.1107/S1600536810027273 |
| _version_ | 1782194320557735936 |
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| author | de Souza, Marcus V. N. Pinheiro, Alessandra C. Tiekink, Edward R. T. Wardell, Solange M. S. V. Wardell, James L. |
| author_facet | de Souza, Marcus V. N. Pinheiro, Alessandra C. Tiekink, Edward R. T. Wardell, Solange M. S. V. Wardell, James L. |
| author_sort | de Souza, Marcus V. N. |
| collection | PubMed |
| description | The carbamate and hydrazone groups in the title compound, C(18)H(18)N(4)O(6), are approximately orthogonal [dihedral angle = 83.3 (4)°], and the carbonyl groups are effectively anti [O=C⋯C=O torsion angle = −116.2 (7)°]. The conformation about the imine bond [1.295 (11) Å] is E. The crystal packing is dominated by O—H⋯O and N—H⋯O hydrogen bonding, which leads to two-dimensional arrays in the ab plane. |
| format | Text |
| id | pubmed-3007287 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30072872010-12-30 Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate de Souza, Marcus V. N. Pinheiro, Alessandra C. Tiekink, Edward R. T. Wardell, Solange M. S. V. Wardell, James L. Acta Crystallogr Sect E Struct Rep Online Organic Papers The carbamate and hydrazone groups in the title compound, C(18)H(18)N(4)O(6), are approximately orthogonal [dihedral angle = 83.3 (4)°], and the carbonyl groups are effectively anti [O=C⋯C=O torsion angle = −116.2 (7)°]. The conformation about the imine bond [1.295 (11) Å] is E. The crystal packing is dominated by O—H⋯O and N—H⋯O hydrogen bonding, which leads to two-dimensional arrays in the ab plane. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007287/ /pubmed/21588334 http://dx.doi.org/10.1107/S1600536810027273 Text en © Souza et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers de Souza, Marcus V. N. Pinheiro, Alessandra C. Tiekink, Edward R. T. Wardell, Solange M. S. V. Wardell, James L. Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate |
| title | Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate |
| title_full | Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate |
| title_fullStr | Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate |
| title_full_unstemmed | Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate |
| title_short | Benzyl N-{(1S)-2-hydroxy-1-[N′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate |
| title_sort | benzyl n-{(1s)-2-hydroxy-1-[n′-(2-nitrobenzylidene)hydrazinylcarbonyl]ethyl}carbamate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007287/ https://www.ncbi.nlm.nih.gov/pubmed/21588334 http://dx.doi.org/10.1107/S1600536810027273 |
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