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Poly[[1-(2-pyrid­yl)ethanone-κ(2) N,O]di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium(II)]

In the title compound, [Cd(NCS)(2)(C(7)H(7)NO)](n), the Cd(2+) ion is six-coordinated by one N,O-bidentate 1-(2-pyridyletahanone ligand, two N-bonded thio­cyanate ions and two S-bonded thio­cyanate ions. In the resulting distorted CdOS(2)N(3) octa­hedron, the N atoms adopt a fac arrangement. The bri...

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Autor principal: Miao, Jian-Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007290/
https://www.ncbi.nlm.nih.gov/pubmed/21588117
http://dx.doi.org/10.1107/S1600536810025225
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author Miao, Jian-Ying
author_facet Miao, Jian-Ying
author_sort Miao, Jian-Ying
collection PubMed
description In the title compound, [Cd(NCS)(2)(C(7)H(7)NO)](n), the Cd(2+) ion is six-coordinated by one N,O-bidentate 1-(2-pyridyletahanone ligand, two N-bonded thio­cyanate ions and two S-bonded thio­cyanate ions. In the resulting distorted CdOS(2)N(3) octa­hedron, the N atoms adopt a fac arrangement. The bridging thio­cyanate ions lead to infinite sheets oriented parallel to (101) in the crystal structure.
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spelling pubmed-30072902010-12-30 Poly[[1-(2-pyrid­yl)ethanone-κ(2) N,O]di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium(II)] Miao, Jian-Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(NCS)(2)(C(7)H(7)NO)](n), the Cd(2+) ion is six-coordinated by one N,O-bidentate 1-(2-pyridyletahanone ligand, two N-bonded thio­cyanate ions and two S-bonded thio­cyanate ions. In the resulting distorted CdOS(2)N(3) octa­hedron, the N atoms adopt a fac arrangement. The bridging thio­cyanate ions lead to infinite sheets oriented parallel to (101) in the crystal structure. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007290/ /pubmed/21588117 http://dx.doi.org/10.1107/S1600536810025225 Text en © Jian-Ying Miao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Miao, Jian-Ying
Poly[[1-(2-pyrid­yl)ethanone-κ(2) N,O]di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium(II)]
title Poly[[1-(2-pyrid­yl)ethanone-κ(2) N,O]di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium(II)]
title_full Poly[[1-(2-pyrid­yl)ethanone-κ(2) N,O]di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium(II)]
title_fullStr Poly[[1-(2-pyrid­yl)ethanone-κ(2) N,O]di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium(II)]
title_full_unstemmed Poly[[1-(2-pyrid­yl)ethanone-κ(2) N,O]di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium(II)]
title_short Poly[[1-(2-pyrid­yl)ethanone-κ(2) N,O]di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium(II)]
title_sort poly[[1-(2-pyrid­yl)ethanone-κ(2) n,o]di-μ(2)-thio­cyanato-κ(2) n:s;κ(2) s:n-cadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007290/
https://www.ncbi.nlm.nih.gov/pubmed/21588117
http://dx.doi.org/10.1107/S1600536810025225
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