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Poly[[1-(2-pyridyl)ethanone-κ(2) N,O]di-μ(2)-thiocyanato-κ(2) N:S;κ(2) S:N-cadmium(II)]
In the title compound, [Cd(NCS)(2)(C(7)H(7)NO)](n), the Cd(2+) ion is six-coordinated by one N,O-bidentate 1-(2-pyridyletahanone ligand, two N-bonded thiocyanate ions and two S-bonded thiocyanate ions. In the resulting distorted CdOS(2)N(3) octahedron, the N atoms adopt a fac arrangement. The bri...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007290/ https://www.ncbi.nlm.nih.gov/pubmed/21588117 http://dx.doi.org/10.1107/S1600536810025225 |
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author | Miao, Jian-Ying |
author_facet | Miao, Jian-Ying |
author_sort | Miao, Jian-Ying |
collection | PubMed |
description | In the title compound, [Cd(NCS)(2)(C(7)H(7)NO)](n), the Cd(2+) ion is six-coordinated by one N,O-bidentate 1-(2-pyridyletahanone ligand, two N-bonded thiocyanate ions and two S-bonded thiocyanate ions. In the resulting distorted CdOS(2)N(3) octahedron, the N atoms adopt a fac arrangement. The bridging thiocyanate ions lead to infinite sheets oriented parallel to (101) in the crystal structure. |
format | Text |
id | pubmed-3007290 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30072902010-12-30 Poly[[1-(2-pyridyl)ethanone-κ(2) N,O]di-μ(2)-thiocyanato-κ(2) N:S;κ(2) S:N-cadmium(II)] Miao, Jian-Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(NCS)(2)(C(7)H(7)NO)](n), the Cd(2+) ion is six-coordinated by one N,O-bidentate 1-(2-pyridyletahanone ligand, two N-bonded thiocyanate ions and two S-bonded thiocyanate ions. In the resulting distorted CdOS(2)N(3) octahedron, the N atoms adopt a fac arrangement. The bridging thiocyanate ions lead to infinite sheets oriented parallel to (101) in the crystal structure. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007290/ /pubmed/21588117 http://dx.doi.org/10.1107/S1600536810025225 Text en © Jian-Ying Miao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Miao, Jian-Ying Poly[[1-(2-pyridyl)ethanone-κ(2) N,O]di-μ(2)-thiocyanato-κ(2) N:S;κ(2) S:N-cadmium(II)] |
title | Poly[[1-(2-pyridyl)ethanone-κ(2)
N,O]di-μ(2)-thiocyanato-κ(2)
N:S;κ(2)
S:N-cadmium(II)] |
title_full | Poly[[1-(2-pyridyl)ethanone-κ(2)
N,O]di-μ(2)-thiocyanato-κ(2)
N:S;κ(2)
S:N-cadmium(II)] |
title_fullStr | Poly[[1-(2-pyridyl)ethanone-κ(2)
N,O]di-μ(2)-thiocyanato-κ(2)
N:S;κ(2)
S:N-cadmium(II)] |
title_full_unstemmed | Poly[[1-(2-pyridyl)ethanone-κ(2)
N,O]di-μ(2)-thiocyanato-κ(2)
N:S;κ(2)
S:N-cadmium(II)] |
title_short | Poly[[1-(2-pyridyl)ethanone-κ(2)
N,O]di-μ(2)-thiocyanato-κ(2)
N:S;κ(2)
S:N-cadmium(II)] |
title_sort | poly[[1-(2-pyridyl)ethanone-κ(2)
n,o]di-μ(2)-thiocyanato-κ(2)
n:s;κ(2)
s:n-cadmium(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007290/ https://www.ncbi.nlm.nih.gov/pubmed/21588117 http://dx.doi.org/10.1107/S1600536810025225 |
work_keys_str_mv | AT miaojianying poly12pyridylethanonek2nodim2thiocyanatok2nsk2sncadmiumii |