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Diaquabis(selenocyanato-κN)bis(pyrimidine-κN)manganese(II)
In the crystal structure of the title compound, [Mn(NCSe)(2)(C(4)H(4)N(2))(2)(H(2)O)(2)], the manganese(II) cation is coordinated by two N-bonded pyrimidine ligands, two N-bonded selenocyanate anions and two O-bonded water molecules in a distorted octahedral coordination mode. The asymmetric unit...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007293/ https://www.ncbi.nlm.nih.gov/pubmed/21588092 http://dx.doi.org/10.1107/S1600536810028941 |
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author | Wriedt, Mario Jess, Inke Näther, Christian |
author_facet | Wriedt, Mario Jess, Inke Näther, Christian |
author_sort | Wriedt, Mario |
collection | PubMed |
description | In the crystal structure of the title compound, [Mn(NCSe)(2)(C(4)H(4)N(2))(2)(H(2)O)(2)], the manganese(II) cation is coordinated by two N-bonded pyrimidine ligands, two N-bonded selenocyanate anions and two O-bonded water molecules in a distorted octahedral coordination mode. The asymmetric unit consists of one manganese(II) cation, located on a centre of inversion, as well as one selenocyanate anion, one water molecule and one pyrimidine ligand in general positions. The crystal structure consists of discrete building blocks of composition [Mn(NCSe)(2)(pyrimidine)(2)(H(2)O)(2)], which are connected into layers parallel to (101) by strong water–pyrimidine O—H⋯N hydrogen bonds. |
format | Text |
id | pubmed-3007293 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30072932010-12-30 Diaquabis(selenocyanato-κN)bis(pyrimidine-κN)manganese(II) Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Mn(NCSe)(2)(C(4)H(4)N(2))(2)(H(2)O)(2)], the manganese(II) cation is coordinated by two N-bonded pyrimidine ligands, two N-bonded selenocyanate anions and two O-bonded water molecules in a distorted octahedral coordination mode. The asymmetric unit consists of one manganese(II) cation, located on a centre of inversion, as well as one selenocyanate anion, one water molecule and one pyrimidine ligand in general positions. The crystal structure consists of discrete building blocks of composition [Mn(NCSe)(2)(pyrimidine)(2)(H(2)O)(2)], which are connected into layers parallel to (101) by strong water–pyrimidine O—H⋯N hydrogen bonds. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007293/ /pubmed/21588092 http://dx.doi.org/10.1107/S1600536810028941 Text en © Wriedt et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wriedt, Mario Jess, Inke Näther, Christian Diaquabis(selenocyanato-κN)bis(pyrimidine-κN)manganese(II) |
title | Diaquabis(selenocyanato-κN)bis(pyrimidine-κN)manganese(II) |
title_full | Diaquabis(selenocyanato-κN)bis(pyrimidine-κN)manganese(II) |
title_fullStr | Diaquabis(selenocyanato-κN)bis(pyrimidine-κN)manganese(II) |
title_full_unstemmed | Diaquabis(selenocyanato-κN)bis(pyrimidine-κN)manganese(II) |
title_short | Diaquabis(selenocyanato-κN)bis(pyrimidine-κN)manganese(II) |
title_sort | diaquabis(selenocyanato-κn)bis(pyrimidine-κn)manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007293/ https://www.ncbi.nlm.nih.gov/pubmed/21588092 http://dx.doi.org/10.1107/S1600536810028941 |
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