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Diaqua­bis­(seleno­cyanato-κN)bis­(pyrimidine-κN)manganese(II)

In the crystal structure of the title compound, [Mn(NCSe)(2)(C(4)H(4)N(2))(2)(H(2)O)(2)], the manganese(II) cation is coordinated by two N-bonded pyrimidine ligands, two N-bonded seleno­cyanate anions and two O-bonded water mol­ecules in a distorted octa­hedral coordination mode. The asymmetric unit...

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Detalles Bibliográficos
Autores principales: Wriedt, Mario, Jess, Inke, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007293/
https://www.ncbi.nlm.nih.gov/pubmed/21588092
http://dx.doi.org/10.1107/S1600536810028941
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author Wriedt, Mario
Jess, Inke
Näther, Christian
author_facet Wriedt, Mario
Jess, Inke
Näther, Christian
author_sort Wriedt, Mario
collection PubMed
description In the crystal structure of the title compound, [Mn(NCSe)(2)(C(4)H(4)N(2))(2)(H(2)O)(2)], the manganese(II) cation is coordinated by two N-bonded pyrimidine ligands, two N-bonded seleno­cyanate anions and two O-bonded water mol­ecules in a distorted octa­hedral coordination mode. The asymmetric unit consists of one manganese(II) cation, located on a centre of inversion, as well as one seleno­cyanate anion, one water mol­ecule and one pyrimidine ligand in general positions. The crystal structure consists of discrete building blocks of composition [Mn(NCSe)(2)(pyrimidine)(2)(H(2)O)(2)], which are connected into layers parallel to (101) by strong water–pyrimidine O—H⋯N hydrogen bonds.
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spelling pubmed-30072932010-12-30 Diaqua­bis­(seleno­cyanato-κN)bis­(pyrimidine-κN)manganese(II) Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Mn(NCSe)(2)(C(4)H(4)N(2))(2)(H(2)O)(2)], the manganese(II) cation is coordinated by two N-bonded pyrimidine ligands, two N-bonded seleno­cyanate anions and two O-bonded water mol­ecules in a distorted octa­hedral coordination mode. The asymmetric unit consists of one manganese(II) cation, located on a centre of inversion, as well as one seleno­cyanate anion, one water mol­ecule and one pyrimidine ligand in general positions. The crystal structure consists of discrete building blocks of composition [Mn(NCSe)(2)(pyrimidine)(2)(H(2)O)(2)], which are connected into layers parallel to (101) by strong water–pyrimidine O—H⋯N hydrogen bonds. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007293/ /pubmed/21588092 http://dx.doi.org/10.1107/S1600536810028941 Text en © Wriedt et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wriedt, Mario
Jess, Inke
Näther, Christian
Diaqua­bis­(seleno­cyanato-κN)bis­(pyrimidine-κN)manganese(II)
title Diaqua­bis­(seleno­cyanato-κN)bis­(pyrimidine-κN)manganese(II)
title_full Diaqua­bis­(seleno­cyanato-κN)bis­(pyrimidine-κN)manganese(II)
title_fullStr Diaqua­bis­(seleno­cyanato-κN)bis­(pyrimidine-κN)manganese(II)
title_full_unstemmed Diaqua­bis­(seleno­cyanato-κN)bis­(pyrimidine-κN)manganese(II)
title_short Diaqua­bis­(seleno­cyanato-κN)bis­(pyrimidine-κN)manganese(II)
title_sort diaqua­bis­(seleno­cyanato-κn)bis­(pyrimidine-κn)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007293/
https://www.ncbi.nlm.nih.gov/pubmed/21588092
http://dx.doi.org/10.1107/S1600536810028941
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