catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ-N,N′-bis­(3-pyridyl­methyl­idene)benzene-1,4-diamine]

In the title compound, [Ag(NO(3))(C(18)H(14)N(4))](n), the Ag(I) atom is coordinated by two N atoms from two N,N′-bis­(3-pyridyl­methyl­idene)benzene-1,4-diamine (bpbd) mol­ecules and two O atoms from a bidentate nitrate anion. The bpbd mol­ecules bridge the Ag atoms into a chain. Two adjacent chain...

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Detalles Bibliográficos
Autores principales: Liu, Yong-Hao, Xu, Quan, Han, Zhi-You
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007296/
https://www.ncbi.nlm.nih.gov/pubmed/21588144
http://dx.doi.org/10.1107/S1600536810025997
Descripción
Sumario:In the title compound, [Ag(NO(3))(C(18)H(14)N(4))](n), the Ag(I) atom is coordinated by two N atoms from two N,N′-bis­(3-pyridyl­methyl­idene)benzene-1,4-diamine (bpbd) mol­ecules and two O atoms from a bidentate nitrate anion. The bpbd mol­ecules bridge the Ag atoms into a chain. Two adjacent chains are further connected by Ag⋯Ag inter­actions [3.1631 (8) Å], forming a double-chain structure. A π–π inter­action [centroid–centroid distance = 3.758 (3) Å] occurs between the double chains. Inter­chain C—H⋯O hydrogen bonds are observed.

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