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catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ-N,N′-bis(3-pyridylmethylidene)benzene-1,4-diamine]
In the title compound, [Ag(NO(3))(C(18)H(14)N(4))](n), the Ag(I) atom is coordinated by two N atoms from two N,N′-bis(3-pyridylmethylidene)benzene-1,4-diamine (bpbd) molecules and two O atoms from a bidentate nitrate anion. The bpbd molecules bridge the Ag atoms into a chain. Two adjacent chain...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007296/ https://www.ncbi.nlm.nih.gov/pubmed/21588144 http://dx.doi.org/10.1107/S1600536810025997 |
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author | Liu, Yong-Hao Xu, Quan Han, Zhi-You |
author_facet | Liu, Yong-Hao Xu, Quan Han, Zhi-You |
author_sort | Liu, Yong-Hao |
collection | PubMed |
description | In the title compound, [Ag(NO(3))(C(18)H(14)N(4))](n), the Ag(I) atom is coordinated by two N atoms from two N,N′-bis(3-pyridylmethylidene)benzene-1,4-diamine (bpbd) molecules and two O atoms from a bidentate nitrate anion. The bpbd molecules bridge the Ag atoms into a chain. Two adjacent chains are further connected by Ag⋯Ag interactions [3.1631 (8) Å], forming a double-chain structure. A π–π interaction [centroid–centroid distance = 3.758 (3) Å] occurs between the double chains. Interchain C—H⋯O hydrogen bonds are observed. |
format | Text |
id | pubmed-3007296 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30072962010-12-30 catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ-N,N′-bis(3-pyridylmethylidene)benzene-1,4-diamine] Liu, Yong-Hao Xu, Quan Han, Zhi-You Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(NO(3))(C(18)H(14)N(4))](n), the Ag(I) atom is coordinated by two N atoms from two N,N′-bis(3-pyridylmethylidene)benzene-1,4-diamine (bpbd) molecules and two O atoms from a bidentate nitrate anion. The bpbd molecules bridge the Ag atoms into a chain. Two adjacent chains are further connected by Ag⋯Ag interactions [3.1631 (8) Å], forming a double-chain structure. A π–π interaction [centroid–centroid distance = 3.758 (3) Å] occurs between the double chains. Interchain C—H⋯O hydrogen bonds are observed. International Union of Crystallography 2010-07-07 /pmc/articles/PMC3007296/ /pubmed/21588144 http://dx.doi.org/10.1107/S1600536810025997 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Yong-Hao Xu, Quan Han, Zhi-You catena-Poly[[(nitrato-κ(2) O,O′)silver(I)]-μ-N,N′-bis(3-pyridylmethylidene)benzene-1,4-diamine] |
title |
catena-Poly[[(nitrato-κ(2)
O,O′)silver(I)]-μ-N,N′-bis(3-pyridylmethylidene)benzene-1,4-diamine] |
title_full |
catena-Poly[[(nitrato-κ(2)
O,O′)silver(I)]-μ-N,N′-bis(3-pyridylmethylidene)benzene-1,4-diamine] |
title_fullStr |
catena-Poly[[(nitrato-κ(2)
O,O′)silver(I)]-μ-N,N′-bis(3-pyridylmethylidene)benzene-1,4-diamine] |
title_full_unstemmed |
catena-Poly[[(nitrato-κ(2)
O,O′)silver(I)]-μ-N,N′-bis(3-pyridylmethylidene)benzene-1,4-diamine] |
title_short |
catena-Poly[[(nitrato-κ(2)
O,O′)silver(I)]-μ-N,N′-bis(3-pyridylmethylidene)benzene-1,4-diamine] |
title_sort | catena-poly[[(nitrato-κ(2)
o,o′)silver(i)]-μ-n,n′-bis(3-pyridylmethylidene)benzene-1,4-diamine] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007296/ https://www.ncbi.nlm.nih.gov/pubmed/21588144 http://dx.doi.org/10.1107/S1600536810025997 |
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