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Diaqua­bis­(4-meth­oxy­benzoato-κO (1))bis­(nicotinamide-κN (1))cobalt(II) dihydrate

In the mononuclear title compound, [Co(C(8)H(7)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Co(II) ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 4-meth­oxy­benzoate anion, one nicotinamide (NA) ligand and one coordinated and one uncoordinated wat...

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Autores principales: Hökelek, Tuncer, Dal, Hakan, Tercan, Barış, Tenlik, Erdinç, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007301/
https://www.ncbi.nlm.nih.gov/pubmed/21588149
http://dx.doi.org/10.1107/S1600536810026462
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author Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Tenlik, Erdinç
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Tenlik, Erdinç
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description In the mononuclear title compound, [Co(C(8)H(7)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Co(II) ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 4-meth­oxy­benzoate anion, one nicotinamide (NA) ligand and one coordinated and one uncoordinated water mol­ecule. All ligands act in a monodentate mode. The four O atoms in the equatorial plane around the Co(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the attached benzene ring is 6.47 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 72.80 (4)°. An O—H⋯O hydrogen bond links the uncoordinated water mol­ecule to one of the carboxyl­ate groups. In the crystal structure, inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network.
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spelling pubmed-30073012010-12-30 Diaqua­bis­(4-meth­oxy­benzoato-κO (1))bis­(nicotinamide-κN (1))cobalt(II) dihydrate Hökelek, Tuncer Dal, Hakan Tercan, Barış Tenlik, Erdinç Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title compound, [Co(C(8)H(7)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Co(II) ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 4-meth­oxy­benzoate anion, one nicotinamide (NA) ligand and one coordinated and one uncoordinated water mol­ecule. All ligands act in a monodentate mode. The four O atoms in the equatorial plane around the Co(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the attached benzene ring is 6.47 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 72.80 (4)°. An O—H⋯O hydrogen bond links the uncoordinated water mol­ecule to one of the carboxyl­ate groups. In the crystal structure, inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007301/ /pubmed/21588149 http://dx.doi.org/10.1107/S1600536810026462 Text en © Hökelek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Tenlik, Erdinç
Necefoğlu, Hacali
Diaqua­bis­(4-meth­oxy­benzoato-κO (1))bis­(nicotinamide-κN (1))cobalt(II) dihydrate
title Diaqua­bis­(4-meth­oxy­benzoato-κO (1))bis­(nicotinamide-κN (1))cobalt(II) dihydrate
title_full Diaqua­bis­(4-meth­oxy­benzoato-κO (1))bis­(nicotinamide-κN (1))cobalt(II) dihydrate
title_fullStr Diaqua­bis­(4-meth­oxy­benzoato-κO (1))bis­(nicotinamide-κN (1))cobalt(II) dihydrate
title_full_unstemmed Diaqua­bis­(4-meth­oxy­benzoato-κO (1))bis­(nicotinamide-κN (1))cobalt(II) dihydrate
title_short Diaqua­bis­(4-meth­oxy­benzoato-κO (1))bis­(nicotinamide-κN (1))cobalt(II) dihydrate
title_sort diaqua­bis­(4-meth­oxy­benzoato-κo (1))bis­(nicotinamide-κn (1))cobalt(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007301/
https://www.ncbi.nlm.nih.gov/pubmed/21588149
http://dx.doi.org/10.1107/S1600536810026462
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