Cargando…
Diaquabis(4-methoxybenzoato-κO (1))bis(nicotinamide-κN (1))cobalt(II) dihydrate
In the mononuclear title compound, [Co(C(8)H(7)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Co(II) ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 4-methoxybenzoate anion, one nicotinamide (NA) ligand and one coordinated and one uncoordinated wat...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007301/ https://www.ncbi.nlm.nih.gov/pubmed/21588149 http://dx.doi.org/10.1107/S1600536810026462 |
_version_ | 1782194323935199232 |
---|---|
author | Hökelek, Tuncer Dal, Hakan Tercan, Barış Tenlik, Erdinç Necefoğlu, Hacali |
author_facet | Hökelek, Tuncer Dal, Hakan Tercan, Barış Tenlik, Erdinç Necefoğlu, Hacali |
author_sort | Hökelek, Tuncer |
collection | PubMed |
description | In the mononuclear title compound, [Co(C(8)H(7)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Co(II) ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 4-methoxybenzoate anion, one nicotinamide (NA) ligand and one coordinated and one uncoordinated water molecule. All ligands act in a monodentate mode. The four O atoms in the equatorial plane around the Co(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 6.47 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 72.80 (4)°. An O—H⋯O hydrogen bond links the uncoordinated water molecule to one of the carboxylate groups. In the crystal structure, intermolecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. |
format | Text |
id | pubmed-3007301 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30073012010-12-30 Diaquabis(4-methoxybenzoato-κO (1))bis(nicotinamide-κN (1))cobalt(II) dihydrate Hökelek, Tuncer Dal, Hakan Tercan, Barış Tenlik, Erdinç Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title compound, [Co(C(8)H(7)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Co(II) ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 4-methoxybenzoate anion, one nicotinamide (NA) ligand and one coordinated and one uncoordinated water molecule. All ligands act in a monodentate mode. The four O atoms in the equatorial plane around the Co(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 6.47 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 72.80 (4)°. An O—H⋯O hydrogen bond links the uncoordinated water molecule to one of the carboxylate groups. In the crystal structure, intermolecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007301/ /pubmed/21588149 http://dx.doi.org/10.1107/S1600536810026462 Text en © Hökelek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hökelek, Tuncer Dal, Hakan Tercan, Barış Tenlik, Erdinç Necefoğlu, Hacali Diaquabis(4-methoxybenzoato-κO (1))bis(nicotinamide-κN (1))cobalt(II) dihydrate |
title | Diaquabis(4-methoxybenzoato-κO
(1))bis(nicotinamide-κN
(1))cobalt(II) dihydrate |
title_full | Diaquabis(4-methoxybenzoato-κO
(1))bis(nicotinamide-κN
(1))cobalt(II) dihydrate |
title_fullStr | Diaquabis(4-methoxybenzoato-κO
(1))bis(nicotinamide-κN
(1))cobalt(II) dihydrate |
title_full_unstemmed | Diaquabis(4-methoxybenzoato-κO
(1))bis(nicotinamide-κN
(1))cobalt(II) dihydrate |
title_short | Diaquabis(4-methoxybenzoato-κO
(1))bis(nicotinamide-κN
(1))cobalt(II) dihydrate |
title_sort | diaquabis(4-methoxybenzoato-κo
(1))bis(nicotinamide-κn
(1))cobalt(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007301/ https://www.ncbi.nlm.nih.gov/pubmed/21588149 http://dx.doi.org/10.1107/S1600536810026462 |
work_keys_str_mv | AT hokelektuncer diaquabis4methoxybenzoatoko1bisnicotinamidekn1cobaltiidihydrate AT dalhakan diaquabis4methoxybenzoatoko1bisnicotinamidekn1cobaltiidihydrate AT tercanbarıs diaquabis4methoxybenzoatoko1bisnicotinamidekn1cobaltiidihydrate AT tenlikerdinc diaquabis4methoxybenzoatoko1bisnicotinamidekn1cobaltiidihydrate AT necefogluhacali diaquabis4methoxybenzoatoko1bisnicotinamidekn1cobaltiidihydrate |