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2-Amino-5-chloropyridinium 4-carboxybutanoate
In the title salt, C(5)H(6)ClN(2) (+)·C(5)H(7)O(4) (−), the 2-amino-5-chloropyridinium cation is essentially planar, with a maximum deviation of 0.010 (3) Å. In the crystal structure, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms of the an...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007307/ https://www.ncbi.nlm.nih.gov/pubmed/21588322 http://dx.doi.org/10.1107/S1600536810027091 |
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author | Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Hemamalini, Madhukar |
collection | PubMed |
description | In the title salt, C(5)H(6)ClN(2) (+)·C(5)H(7)O(4) (−), the 2-amino-5-chloropyridinium cation is essentially planar, with a maximum deviation of 0.010 (3) Å. In the crystal structure, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms of the anion via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are further connected via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, forming a layer parallel to the bc plane. In the layer, the hydrogen glutarate anions self-assemble via O—H⋯O hydrogen bonds, forming a supramolecular chain along the c axis. Furthermore, the cations and anions are stacked down along the a axis, forming a three-dimensional network. |
format | Text |
id | pubmed-3007307 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30073072010-12-30 2-Amino-5-chloropyridinium 4-carboxybutanoate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(5)H(6)ClN(2) (+)·C(5)H(7)O(4) (−), the 2-amino-5-chloropyridinium cation is essentially planar, with a maximum deviation of 0.010 (3) Å. In the crystal structure, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms of the anion via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are further connected via O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, forming a layer parallel to the bc plane. In the layer, the hydrogen glutarate anions self-assemble via O—H⋯O hydrogen bonds, forming a supramolecular chain along the c axis. Furthermore, the cations and anions are stacked down along the a axis, forming a three-dimensional network. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007307/ /pubmed/21588322 http://dx.doi.org/10.1107/S1600536810027091 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hemamalini, Madhukar Fun, Hoong-Kun 2-Amino-5-chloropyridinium 4-carboxybutanoate |
title | 2-Amino-5-chloropyridinium 4-carboxybutanoate |
title_full | 2-Amino-5-chloropyridinium 4-carboxybutanoate |
title_fullStr | 2-Amino-5-chloropyridinium 4-carboxybutanoate |
title_full_unstemmed | 2-Amino-5-chloropyridinium 4-carboxybutanoate |
title_short | 2-Amino-5-chloropyridinium 4-carboxybutanoate |
title_sort | 2-amino-5-chloropyridinium 4-carboxybutanoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007307/ https://www.ncbi.nlm.nih.gov/pubmed/21588322 http://dx.doi.org/10.1107/S1600536810027091 |
work_keys_str_mv | AT hemamalinimadhukar 2amino5chloropyridinium4carboxybutanoate AT funhoongkun 2amino5chloropyridinium4carboxybutanoate |