trans-K(3)[TcO(2)(CN)(4)]

The structure of the title compound, tripotassium trans-tetra­cyanidodioxidotechnetate(V), is isotypic with its Re analogue. The [TcO(2)(CN)(4)](3−) trans-tetra­cyanido­dioxido­technetate anion has a slightly distorted octa­hedral configuration. The Tc atom is located on a center of inversion and is...

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Detalles Bibliográficos
Autores principales: Chatterjee, Sayandev, Del Negro, Andrew S., Edwards, Matthew K., Twamley, Brendan, Krause, Jeanette A., Bryan, Samuel A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007308/
https://www.ncbi.nlm.nih.gov/pubmed/21588082
http://dx.doi.org/10.1107/S1600536810028205
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author Chatterjee, Sayandev
Del Negro, Andrew S.
Edwards, Matthew K.
Twamley, Brendan
Krause, Jeanette A.
Bryan, Samuel A.
author_facet Chatterjee, Sayandev
Del Negro, Andrew S.
Edwards, Matthew K.
Twamley, Brendan
Krause, Jeanette A.
Bryan, Samuel A.
author_sort Chatterjee, Sayandev
collection PubMed
description The structure of the title compound, tripotassium trans-tetra­cyanidodioxidotechnetate(V), is isotypic with its Re analogue. The [TcO(2)(CN)(4)](3−) trans-tetra­cyanido­dioxido­technetate anion has a slightly distorted octa­hedral configuration. The Tc atom is located on a center of inversion and is bound to two O atoms in axial and to four cyanide ligands in equatorial positions. The Tc—O distance is consistent with a double-bond character. The two potassium cations, one located on a center of inversion and one in a general position, reside in octa­hedral or tetra­hedral environments, respectively. K⋯O and K⋯N inter­actions occur in the 2.7877 (19)–2.8598 (15) Å range.
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spelling pubmed-30073082010-12-30 trans-K(3)[TcO(2)(CN)(4)] Chatterjee, Sayandev Del Negro, Andrew S. Edwards, Matthew K. Twamley, Brendan Krause, Jeanette A. Bryan, Samuel A. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The structure of the title compound, tripotassium trans-tetra­cyanidodioxidotechnetate(V), is isotypic with its Re analogue. The [TcO(2)(CN)(4)](3−) trans-tetra­cyanido­dioxido­technetate anion has a slightly distorted octa­hedral configuration. The Tc atom is located on a center of inversion and is bound to two O atoms in axial and to four cyanide ligands in equatorial positions. The Tc—O distance is consistent with a double-bond character. The two potassium cations, one located on a center of inversion and one in a general position, reside in octa­hedral or tetra­hedral environments, respectively. K⋯O and K⋯N inter­actions occur in the 2.7877 (19)–2.8598 (15) Å range. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007308/ /pubmed/21588082 http://dx.doi.org/10.1107/S1600536810028205 Text en © Chatterjee et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Chatterjee, Sayandev
Del Negro, Andrew S.
Edwards, Matthew K.
Twamley, Brendan
Krause, Jeanette A.
Bryan, Samuel A.
trans-K(3)[TcO(2)(CN)(4)]
title trans-K(3)[TcO(2)(CN)(4)]
title_full trans-K(3)[TcO(2)(CN)(4)]
title_fullStr trans-K(3)[TcO(2)(CN)(4)]
title_full_unstemmed trans-K(3)[TcO(2)(CN)(4)]
title_short trans-K(3)[TcO(2)(CN)(4)]
title_sort trans-k(3)[tco(2)(cn)(4)]
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007308/
https://www.ncbi.nlm.nih.gov/pubmed/21588082
http://dx.doi.org/10.1107/S1600536810028205
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AT krausejeanettea transk3tco2cn4
AT bryansamuela transk3tco2cn4

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