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Bis(isonicotinamide-κN (1))bis­(4-methyl­benzoato-κO)copper(II) dihydrate

In the centrosymmetric title compound, [Cu(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)(2)]·2H(2)O, the Cu(II) ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 4-methyl­benzoate anion, one isonicotinamide (INA) ligand and one uncoordinated water mol­ecule; all the li...

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Detalles Bibliográficos
Autores principales: Hökelek, Tuncer, Saka, Güner, Tercan, Barış, Çimen, Efdal, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007312/
https://www.ncbi.nlm.nih.gov/pubmed/21588184
http://dx.doi.org/10.1107/S1600536810028060
Descripción
Sumario:In the centrosymmetric title compound, [Cu(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)(2)]·2H(2)O, the Cu(II) ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 4-methyl­benzoate anion, one isonicotinamide (INA) ligand and one uncoordinated water mol­ecule; all the ligands are monodentate. The two O and the two N atoms around the Cu(II) ion form a slightly distorted square-planar arrangement. The dihedral angle between the carboxyl­ate group and the attached benzene ring is 13.86 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 86.08 (5)°. The uncoordinated water mol­ecules are linked to the INA ligands by O—H⋯O hydrogen bonds. In the crystal structure, inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network.