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Bis{1-[(E)-(2-methylphenyl)diazenyl]-2-naphtholato}palladium(II)
In the title compound, [Pd(C(17)H(13)N(2)O)(2)], the Pd(II) atom is tetracoordinated by two N atoms and two O atoms from two bidentate methylphenyldiazenylnaphtolate ligands, forming a square-planar complex. The two N atoms and two O atoms around the Pd(II) atom are trans to each other (as the Pd(...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007315/ https://www.ncbi.nlm.nih.gov/pubmed/21588097 http://dx.doi.org/10.1107/S1600536810028916 |
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author | Lin, Meng-Ling Tsai, Chen-Yen Li, Chen-Yu Huang, Bor-Hunn Ko, Bao-Tsan |
author_facet | Lin, Meng-Ling Tsai, Chen-Yen Li, Chen-Yu Huang, Bor-Hunn Ko, Bao-Tsan |
author_sort | Lin, Meng-Ling |
collection | PubMed |
description | In the title compound, [Pd(C(17)H(13)N(2)O)(2)], the Pd(II) atom is tetracoordinated by two N atoms and two O atoms from two bidentate methylphenyldiazenylnaphtolate ligands, forming a square-planar complex. The two N atoms and two O atoms around the Pd(II) atom are trans to each other (as the Pd(II) atom lies on a crystallographic inversion centre) with O—Pd—N bond angles of 89.60 (11) and 90.40 (11)°. The distances between the Pd(II) atom and the coordinated O and N atoms are 1.966 (3) and 2.009 (3) Å, respectively. |
format | Text |
id | pubmed-3007315 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30073152010-12-30 Bis{1-[(E)-(2-methylphenyl)diazenyl]-2-naphtholato}palladium(II) Lin, Meng-Ling Tsai, Chen-Yen Li, Chen-Yu Huang, Bor-Hunn Ko, Bao-Tsan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(17)H(13)N(2)O)(2)], the Pd(II) atom is tetracoordinated by two N atoms and two O atoms from two bidentate methylphenyldiazenylnaphtolate ligands, forming a square-planar complex. The two N atoms and two O atoms around the Pd(II) atom are trans to each other (as the Pd(II) atom lies on a crystallographic inversion centre) with O—Pd—N bond angles of 89.60 (11) and 90.40 (11)°. The distances between the Pd(II) atom and the coordinated O and N atoms are 1.966 (3) and 2.009 (3) Å, respectively. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007315/ /pubmed/21588097 http://dx.doi.org/10.1107/S1600536810028916 Text en © Lin et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lin, Meng-Ling Tsai, Chen-Yen Li, Chen-Yu Huang, Bor-Hunn Ko, Bao-Tsan Bis{1-[(E)-(2-methylphenyl)diazenyl]-2-naphtholato}palladium(II) |
title | Bis{1-[(E)-(2-methylphenyl)diazenyl]-2-naphtholato}palladium(II) |
title_full | Bis{1-[(E)-(2-methylphenyl)diazenyl]-2-naphtholato}palladium(II) |
title_fullStr | Bis{1-[(E)-(2-methylphenyl)diazenyl]-2-naphtholato}palladium(II) |
title_full_unstemmed | Bis{1-[(E)-(2-methylphenyl)diazenyl]-2-naphtholato}palladium(II) |
title_short | Bis{1-[(E)-(2-methylphenyl)diazenyl]-2-naphtholato}palladium(II) |
title_sort | bis{1-[(e)-(2-methylphenyl)diazenyl]-2-naphtholato}palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007315/ https://www.ncbi.nlm.nih.gov/pubmed/21588097 http://dx.doi.org/10.1107/S1600536810028916 |
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