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Bis(2-amino-4-methylpyridinium) terephthalate tetrahydrate
In the crystal structure of the title salt, 2C(6)H(9)N(2) (+)·C(8)H(4)O(4) (2−)·4H(2)O, the terephthalate carboxylate groups interacts with the 2-amino-4-methylpyridinium cations via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The water molecules form an R (6) (6)(12) rin...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007316/ https://www.ncbi.nlm.nih.gov/pubmed/21588255 http://dx.doi.org/10.1107/S1600536810025651 |
Sumario: | In the crystal structure of the title salt, 2C(6)H(9)N(2) (+)·C(8)H(4)O(4) (2−)·4H(2)O, the terephthalate carboxylate groups interacts with the 2-amino-4-methylpyridinium cations via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The water molecules form an R (6) (6)(12) ring motif through O—H⋯O hydrogen bonds and these motifs are fused, forming a supramolecular chain along the c axis. The R (2) (2)(8) and R (6) (6)(12) ring motifs are connected via O—H⋯O hydrogen bonds. In addition, π–π stacking interactions are observed between the pyridinium rings [centroid–centroid distance = 3.522 (12) Å]. |
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