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(Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)cerium(III)

The asymmetric unit of title compound, [Ce(NO(3))(3)(C(15)H(15)NO(2))(2)(CH(3)OH)], consists of two Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolate (HL) ligands, three nitrate anions and a methanol ligand. The Ce(III) ion is 11-coordinated: three nitrate radical anions coordinate...

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Detalles Bibliográficos
Autores principales: Liu, Jia-Lu, Liu, Jian-Feng, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007323/
https://www.ncbi.nlm.nih.gov/pubmed/21588168
http://dx.doi.org/10.1107/S1600536810026139
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author Liu, Jia-Lu
Liu, Jian-Feng
Zhao, Guo-Liang
author_facet Liu, Jia-Lu
Liu, Jian-Feng
Zhao, Guo-Liang
author_sort Liu, Jia-Lu
collection PubMed
description The asymmetric unit of title compound, [Ce(NO(3))(3)(C(15)H(15)NO(2))(2)(CH(3)OH)], consists of two Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolate (HL) ligands, three nitrate anions and a methanol ligand. The Ce(III) ion is 11-coordinated: three nitrate radical anions coordinate to the Ce(III) ion through O atoms, two HL ligands chelate the Ce(III) ion through the O atoms of the phenolate and meth­oxy groups, and one methanol mol­ecule coordinates to Ce(III) ion through its O atom. The O atom of one nitrate anion is disordered over two sites of equal occupancy. The protonated imine N atoms are involved in intra­molecular hydrogen bonds with the phenoxide groups. C—H⋯O inter­actions are also observed.
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spelling pubmed-30073232010-12-30 (Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)cerium(III) Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of title compound, [Ce(NO(3))(3)(C(15)H(15)NO(2))(2)(CH(3)OH)], consists of two Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolate (HL) ligands, three nitrate anions and a methanol ligand. The Ce(III) ion is 11-coordinated: three nitrate radical anions coordinate to the Ce(III) ion through O atoms, two HL ligands chelate the Ce(III) ion through the O atoms of the phenolate and meth­oxy groups, and one methanol mol­ecule coordinates to Ce(III) ion through its O atom. The O atom of one nitrate anion is disordered over two sites of equal occupancy. The protonated imine N atoms are involved in intra­molecular hydrogen bonds with the phenoxide groups. C—H⋯O inter­actions are also observed. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007323/ /pubmed/21588168 http://dx.doi.org/10.1107/S1600536810026139 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Jia-Lu
Liu, Jian-Feng
Zhao, Guo-Liang
(Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)cerium(III)
title (Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)cerium(III)
title_full (Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)cerium(III)
title_fullStr (Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)cerium(III)
title_full_unstemmed (Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)cerium(III)
title_short (Methanol-κO)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)cerium(III)
title_sort (methanol-κo)bis­{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolato-κ(2) o,o′}tris­(nitrato-κ(2) o,o′)cerium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007323/
https://www.ncbi.nlm.nih.gov/pubmed/21588168
http://dx.doi.org/10.1107/S1600536810026139
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