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(Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2) O,O′}tris(nitrato-κ(2) O,O′)cerium(III)
The asymmetric unit of title compound, [Ce(NO(3))(3)(C(15)H(15)NO(2))(2)(CH(3)OH)], consists of two Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate (HL) ligands, three nitrate anions and a methanol ligand. The Ce(III) ion is 11-coordinated: three nitrate radical anions coordinate...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007323/ https://www.ncbi.nlm.nih.gov/pubmed/21588168 http://dx.doi.org/10.1107/S1600536810026139 |
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author | Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang |
author_facet | Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang |
author_sort | Liu, Jia-Lu |
collection | PubMed |
description | The asymmetric unit of title compound, [Ce(NO(3))(3)(C(15)H(15)NO(2))(2)(CH(3)OH)], consists of two Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate (HL) ligands, three nitrate anions and a methanol ligand. The Ce(III) ion is 11-coordinated: three nitrate radical anions coordinate to the Ce(III) ion through O atoms, two HL ligands chelate the Ce(III) ion through the O atoms of the phenolate and methoxy groups, and one methanol molecule coordinates to Ce(III) ion through its O atom. The O atom of one nitrate anion is disordered over two sites of equal occupancy. The protonated imine N atoms are involved in intramolecular hydrogen bonds with the phenoxide groups. C—H⋯O interactions are also observed. |
format | Text |
id | pubmed-3007323 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30073232010-12-30 (Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2) O,O′}tris(nitrato-κ(2) O,O′)cerium(III) Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of title compound, [Ce(NO(3))(3)(C(15)H(15)NO(2))(2)(CH(3)OH)], consists of two Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate (HL) ligands, three nitrate anions and a methanol ligand. The Ce(III) ion is 11-coordinated: three nitrate radical anions coordinate to the Ce(III) ion through O atoms, two HL ligands chelate the Ce(III) ion through the O atoms of the phenolate and methoxy groups, and one methanol molecule coordinates to Ce(III) ion through its O atom. The O atom of one nitrate anion is disordered over two sites of equal occupancy. The protonated imine N atoms are involved in intramolecular hydrogen bonds with the phenoxide groups. C—H⋯O interactions are also observed. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007323/ /pubmed/21588168 http://dx.doi.org/10.1107/S1600536810026139 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang (Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2) O,O′}tris(nitrato-κ(2) O,O′)cerium(III) |
title | (Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(nitrato-κ(2)
O,O′)cerium(III) |
title_full | (Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(nitrato-κ(2)
O,O′)cerium(III) |
title_fullStr | (Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(nitrato-κ(2)
O,O′)cerium(III) |
title_full_unstemmed | (Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(nitrato-κ(2)
O,O′)cerium(III) |
title_short | (Methanol-κO)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
O,O′}tris(nitrato-κ(2)
O,O′)cerium(III) |
title_sort | (methanol-κo)bis{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ(2)
o,o′}tris(nitrato-κ(2)
o,o′)cerium(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007323/ https://www.ncbi.nlm.nih.gov/pubmed/21588168 http://dx.doi.org/10.1107/S1600536810026139 |
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