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[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(nitrito-κ(2) O,O′)cadmium(II)

In the title complex, [Cd(NO(2))(2)(C(17)H(14)N(4))], the Cd(II) ion assumes a distorted monocapped octa­hedral coordination geometry defined by an N(3)O(4) donor set. The crystal structure is stabilized by π–π stacking inter­actions [shortest centroid–centroid distance = 3.5537 (18) Å]....

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Detalles Bibliográficos
Autores principales: Shi, Jing Min, Meng, Lin, Wang, Yu Qing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007325/
https://www.ncbi.nlm.nih.gov/pubmed/21588125
http://dx.doi.org/10.1107/S160053681002550X
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author Shi, Jing Min
Meng, Lin
Wang, Yu Qing
author_facet Shi, Jing Min
Meng, Lin
Wang, Yu Qing
author_sort Shi, Jing Min
collection PubMed
description In the title complex, [Cd(NO(2))(2)(C(17)H(14)N(4))], the Cd(II) ion assumes a distorted monocapped octa­hedral coordination geometry defined by an N(3)O(4) donor set. The crystal structure is stabilized by π–π stacking inter­actions [shortest centroid–centroid distance = 3.5537 (18) Å].
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spelling pubmed-30073252010-12-30 [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(nitrito-κ(2) O,O′)cadmium(II) Shi, Jing Min Meng, Lin Wang, Yu Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(NO(2))(2)(C(17)H(14)N(4))], the Cd(II) ion assumes a distorted monocapped octa­hedral coordination geometry defined by an N(3)O(4) donor set. The crystal structure is stabilized by π–π stacking inter­actions [shortest centroid–centroid distance = 3.5537 (18) Å]. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007325/ /pubmed/21588125 http://dx.doi.org/10.1107/S160053681002550X Text en © Shi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Jing Min
Meng, Lin
Wang, Yu Qing
[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(nitrito-κ(2) O,O′)cadmium(II)
title [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(nitrito-κ(2) O,O′)cadmium(II)
title_full [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(nitrito-κ(2) O,O′)cadmium(II)
title_fullStr [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(nitrito-κ(2) O,O′)cadmium(II)
title_full_unstemmed [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(nitrito-κ(2) O,O′)cadmium(II)
title_short [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(nitrito-κ(2) O,O′)cadmium(II)
title_sort [2-(3,5-dimethyl-1h-pyrazol-1-yl-κn (2))-1,10-phenanthroline-κ(2) n,n′]bis­(nitrito-κ(2) o,o′)cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007325/
https://www.ncbi.nlm.nih.gov/pubmed/21588125
http://dx.doi.org/10.1107/S160053681002550X
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