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[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis(nitrito-κ(2) O,O′)cadmium(II)
In the title complex, [Cd(NO(2))(2)(C(17)H(14)N(4))], the Cd(II) ion assumes a distorted monocapped octahedral coordination geometry defined by an N(3)O(4) donor set. The crystal structure is stabilized by π–π stacking interactions [shortest centroid–centroid distance = 3.5537 (18) Å]....
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007325/ https://www.ncbi.nlm.nih.gov/pubmed/21588125 http://dx.doi.org/10.1107/S160053681002550X |
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author | Shi, Jing Min Meng, Lin Wang, Yu Qing |
author_facet | Shi, Jing Min Meng, Lin Wang, Yu Qing |
author_sort | Shi, Jing Min |
collection | PubMed |
description | In the title complex, [Cd(NO(2))(2)(C(17)H(14)N(4))], the Cd(II) ion assumes a distorted monocapped octahedral coordination geometry defined by an N(3)O(4) donor set. The crystal structure is stabilized by π–π stacking interactions [shortest centroid–centroid distance = 3.5537 (18) Å]. |
format | Text |
id | pubmed-3007325 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30073252010-12-30 [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis(nitrito-κ(2) O,O′)cadmium(II) Shi, Jing Min Meng, Lin Wang, Yu Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(NO(2))(2)(C(17)H(14)N(4))], the Cd(II) ion assumes a distorted monocapped octahedral coordination geometry defined by an N(3)O(4) donor set. The crystal structure is stabilized by π–π stacking interactions [shortest centroid–centroid distance = 3.5537 (18) Å]. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007325/ /pubmed/21588125 http://dx.doi.org/10.1107/S160053681002550X Text en © Shi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shi, Jing Min Meng, Lin Wang, Yu Qing [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis(nitrito-κ(2) O,O′)cadmium(II) |
title | [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]bis(nitrito-κ(2)
O,O′)cadmium(II) |
title_full | [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]bis(nitrito-κ(2)
O,O′)cadmium(II) |
title_fullStr | [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]bis(nitrito-κ(2)
O,O′)cadmium(II) |
title_full_unstemmed | [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]bis(nitrito-κ(2)
O,O′)cadmium(II) |
title_short | [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′]bis(nitrito-κ(2)
O,O′)cadmium(II) |
title_sort | [2-(3,5-dimethyl-1h-pyrazol-1-yl-κn
(2))-1,10-phenanthroline-κ(2)
n,n′]bis(nitrito-κ(2)
o,o′)cadmium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007325/ https://www.ncbi.nlm.nih.gov/pubmed/21588125 http://dx.doi.org/10.1107/S160053681002550X |
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