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3-Chloro-6-[(E)-2-(1-phenylethylidene)hydrazinyl]pyridazine
Two independent molecules are present in the asymmetric unit of the title compound, C(12)H(11)ClN(4), (Z′ = 2): the dihedral angles between the phenyl and pyridizine rings are 8.35 (10) and 37.64 (6)°. In the crystal, the two molecules form inversion dimers with R (2) (2)(8) ring motifs through in...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007326/ https://www.ncbi.nlm.nih.gov/pubmed/21588398 http://dx.doi.org/10.1107/S1600536810024402 |
Sumario: | Two independent molecules are present in the asymmetric unit of the title compound, C(12)H(11)ClN(4), (Z′ = 2): the dihedral angles between the phenyl and pyridizine rings are 8.35 (10) and 37.64 (6)°. In the crystal, the two molecules form inversion dimers with R (2) (2)(8) ring motifs through intermolecular N—H⋯N hydrogen bonds. The crystal structure is stabilized by π–π interactions between the pyridazine rings of symmetry-related molecules. In one of the independent molecules, the centroid–centroid separations are 3.6927 (13) and 3.7961 (13) Å, whereas in the other, the separations are 3.6909 (13) and 3.9059 (13) Å. |
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