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Dibromidobis(N,N,N′,N′-tetra­methyl­thio­urea-κS)cadmium(II)

In the title compound, [CdBr(2)(C(5)H(12)N(2)S)(2)], the Cd(II) atom lies on a twofold rotation axis. It exhibits a distorted tetra­hedral coordination environment defined by two S atoms of two tetra­methyl­thio­urea (tmtu) ligands and two bromide ions. The crystal structure is consolidated by C—H⋯N...

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Detalles Bibliográficos
Autores principales: Nawaz, Sidra, Sadaf, Sana, Fettouhi, Mohammed, Fazal, Atif, Ahmad, Saeed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007332/
https://www.ncbi.nlm.nih.gov/pubmed/21588180
http://dx.doi.org/10.1107/S1600536810028102
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author Nawaz, Sidra
Sadaf, Sana
Fettouhi, Mohammed
Fazal, Atif
Ahmad, Saeed
author_facet Nawaz, Sidra
Sadaf, Sana
Fettouhi, Mohammed
Fazal, Atif
Ahmad, Saeed
author_sort Nawaz, Sidra
collection PubMed
description In the title compound, [CdBr(2)(C(5)H(12)N(2)S)(2)], the Cd(II) atom lies on a twofold rotation axis. It exhibits a distorted tetra­hedral coordination environment defined by two S atoms of two tetra­methyl­thio­urea (tmtu) ligands and two bromide ions. The crystal structure is consolidated by C—H⋯N and C—H⋯S hydrogen bonds.
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spelling pubmed-30073322010-12-30 Dibromidobis(N,N,N′,N′-tetra­methyl­thio­urea-κS)cadmium(II) Nawaz, Sidra Sadaf, Sana Fettouhi, Mohammed Fazal, Atif Ahmad, Saeed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdBr(2)(C(5)H(12)N(2)S)(2)], the Cd(II) atom lies on a twofold rotation axis. It exhibits a distorted tetra­hedral coordination environment defined by two S atoms of two tetra­methyl­thio­urea (tmtu) ligands and two bromide ions. The crystal structure is consolidated by C—H⋯N and C—H⋯S hydrogen bonds. International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007332/ /pubmed/21588180 http://dx.doi.org/10.1107/S1600536810028102 Text en © Nawaz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nawaz, Sidra
Sadaf, Sana
Fettouhi, Mohammed
Fazal, Atif
Ahmad, Saeed
Dibromidobis(N,N,N′,N′-tetra­methyl­thio­urea-κS)cadmium(II)
title Dibromidobis(N,N,N′,N′-tetra­methyl­thio­urea-κS)cadmium(II)
title_full Dibromidobis(N,N,N′,N′-tetra­methyl­thio­urea-κS)cadmium(II)
title_fullStr Dibromidobis(N,N,N′,N′-tetra­methyl­thio­urea-κS)cadmium(II)
title_full_unstemmed Dibromidobis(N,N,N′,N′-tetra­methyl­thio­urea-κS)cadmium(II)
title_short Dibromidobis(N,N,N′,N′-tetra­methyl­thio­urea-κS)cadmium(II)
title_sort dibromidobis(n,n,n′,n′-tetra­methyl­thio­urea-κs)cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007332/
https://www.ncbi.nlm.nih.gov/pubmed/21588180
http://dx.doi.org/10.1107/S1600536810028102
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