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Nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-μ-bis­(diphenyl­arsino)methane-1:2κ(2) As:As’-[tris­(2-chloro­eth­yl) phosphite-3κP]-triangulo-triruthenium(0)

In the title triangulo-triruthenium(0) compound, [Ru(3)(C(25)H(22)As(2))(C(6)H(12)Cl(3)O(3)P)(CO)(9)], the bis­(diphenyl­arsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to t...

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Detalles Bibliográficos
Autores principales: Shawkataly, Omar bin, Khan, Imthyaz Ahmed, Sirat, Siti Syaida, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007339/
https://www.ncbi.nlm.nih.gov/pubmed/21588162
http://dx.doi.org/10.1107/S1600536810026267
Descripción
Sumario:In the title triangulo-triruthenium(0) compound, [Ru(3)(C(25)H(22)As(2))(C(6)H(12)Cl(3)O(3)P)(CO)(9)], the bis­(diphenyl­arsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. In the crystal packing, the mol­ecules are linked by inter­molecular C—H⋯O hydrogen bonds into a three-dimensional framework. Weak inter­molecular C—H⋯π inter­actions further stabilize the crystal structure.