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Nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-μ-bis(diphenylarsino)methane-1:2κ(2) As:As’-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0)
In the title triangulo-triruthenium(0) compound, [Ru(3)(C(25)H(22)As(2))(C(6)H(12)Cl(3)O(3)P)(CO)(9)], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to t...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007339/ https://www.ncbi.nlm.nih.gov/pubmed/21588162 http://dx.doi.org/10.1107/S1600536810026267 |
| _version_ | 1782194333014818816 |
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| author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun |
| author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun |
| author_sort | Shawkataly, Omar bin |
| collection | PubMed |
| description | In the title triangulo-triruthenium(0) compound, [Ru(3)(C(25)H(22)As(2))(C(6)H(12)Cl(3)O(3)P)(CO)(9)], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. In the crystal packing, the molecules are linked by intermolecular C—H⋯O hydrogen bonds into a three-dimensional framework. Weak intermolecular C—H⋯π interactions further stabilize the crystal structure. |
| format | Text |
| id | pubmed-3007339 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30073392010-12-30 Nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-μ-bis(diphenylarsino)methane-1:2κ(2) As:As’-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title triangulo-triruthenium(0) compound, [Ru(3)(C(25)H(22)As(2))(C(6)H(12)Cl(3)O(3)P)(CO)(9)], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphine ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. In the crystal packing, the molecules are linked by intermolecular C—H⋯O hydrogen bonds into a three-dimensional framework. Weak intermolecular C—H⋯π interactions further stabilize the crystal structure. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007339/ /pubmed/21588162 http://dx.doi.org/10.1107/S1600536810026267 Text en © Shawkataly et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun Nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-μ-bis(diphenylarsino)methane-1:2κ(2) As:As’-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0) |
| title | Nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-μ-bis(diphenylarsino)methane-1:2κ(2)
As:As’-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0) |
| title_full | Nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-μ-bis(diphenylarsino)methane-1:2κ(2)
As:As’-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0) |
| title_fullStr | Nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-μ-bis(diphenylarsino)methane-1:2κ(2)
As:As’-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0) |
| title_full_unstemmed | Nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-μ-bis(diphenylarsino)methane-1:2κ(2)
As:As’-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0) |
| title_short | Nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-μ-bis(diphenylarsino)methane-1:2κ(2)
As:As’-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0) |
| title_sort | nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-μ-bis(diphenylarsino)methane-1:2κ(2)
as:as’-[tris(2-chloroethyl) phosphite-3κp]-triangulo-triruthenium(0) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007339/ https://www.ncbi.nlm.nih.gov/pubmed/21588162 http://dx.doi.org/10.1107/S1600536810026267 |
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