Bromido{N-methyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}­(thio­cyanato-κN)­copper(II)

In the title mononuclear copper(II) compound, [CuBr(NCS)(C(10)H(15)N(3))], the Cu(II) atom is five-coordinated by three N atoms of the Schiff base ligand, the N atom of a thio­cyanate ligand and by one bromide ion forming a distorted square-pyramidal geometry. In the crystal structure, mol­ecules ar...

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Detalles Bibliográficos
Autor principal: Liu, Li-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007341/
https://www.ncbi.nlm.nih.gov/pubmed/21588171
http://dx.doi.org/10.1107/S1600536810027534
Descripción
Sumario:In the title mononuclear copper(II) compound, [CuBr(NCS)(C(10)H(15)N(3))], the Cu(II) atom is five-coordinated by three N atoms of the Schiff base ligand, the N atom of a thio­cyanate ligand and by one bromide ion forming a distorted square-pyramidal geometry. In the crystal structure, mol­ecules are linked through inter­molecular N—H⋯Br hydrogen bonds into chains propagating along [101].

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