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Bromido{N-methyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}(thiocyanato-κN)copper(II)
In the title mononuclear copper(II) compound, [CuBr(NCS)(C(10)H(15)N(3))], the Cu(II) atom is five-coordinated by three N atoms of the Schiff base ligand, the N atom of a thiocyanate ligand and by one bromide ion forming a distorted square-pyramidal geometry. In the crystal structure, molecules ar...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007341/ https://www.ncbi.nlm.nih.gov/pubmed/21588171 http://dx.doi.org/10.1107/S1600536810027534 |
| _version_ | 1782194333507649536 |
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| author | Liu, Li-Jun |
| author_facet | Liu, Li-Jun |
| author_sort | Liu, Li-Jun |
| collection | PubMed |
| description | In the title mononuclear copper(II) compound, [CuBr(NCS)(C(10)H(15)N(3))], the Cu(II) atom is five-coordinated by three N atoms of the Schiff base ligand, the N atom of a thiocyanate ligand and by one bromide ion forming a distorted square-pyramidal geometry. In the crystal structure, molecules are linked through intermolecular N—H⋯Br hydrogen bonds into chains propagating along [101]. |
| format | Text |
| id | pubmed-3007341 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30073412010-12-30 Bromido{N-methyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}(thiocyanato-κN)copper(II) Liu, Li-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear copper(II) compound, [CuBr(NCS)(C(10)H(15)N(3))], the Cu(II) atom is five-coordinated by three N atoms of the Schiff base ligand, the N atom of a thiocyanate ligand and by one bromide ion forming a distorted square-pyramidal geometry. In the crystal structure, molecules are linked through intermolecular N—H⋯Br hydrogen bonds into chains propagating along [101]. International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007341/ /pubmed/21588171 http://dx.doi.org/10.1107/S1600536810027534 Text en © Li-Jun Liu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Li-Jun Bromido{N-methyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}(thiocyanato-κN)copper(II) |
| title | Bromido{N-methyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}(thiocyanato-κN)copper(II) |
| title_full | Bromido{N-methyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}(thiocyanato-κN)copper(II) |
| title_fullStr | Bromido{N-methyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}(thiocyanato-κN)copper(II) |
| title_full_unstemmed | Bromido{N-methyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}(thiocyanato-κN)copper(II) |
| title_short | Bromido{N-methyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}(thiocyanato-κN)copper(II) |
| title_sort | bromido{n-methyl-n′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3)
n,n′,n′′}(thiocyanato-κn)copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007341/ https://www.ncbi.nlm.nih.gov/pubmed/21588171 http://dx.doi.org/10.1107/S1600536810027534 |
| work_keys_str_mv | AT liulijun bromidonmethyln12pyridylethylideneethane12diaminek3nnnthiocyanatokncopperii |