Bis[N-(4-chloro­phen­yl)pyridine-3-carboxamide]­silver(I) nitrate

In the title compound, [Ag(C(12)H(9)ClN(2)O)(2)]NO(3), two N atoms from two pyridine rings of two N-(4-chloro­phen­yl)pyridine-3-carboxamide ligands coordinate to the Ag(I) atom, forming a nearly linear geometry with an N—Ag—N angle of 173.41 (7)°. The crystal structure is stabilized by N—H⋯O, C—H⋯O...

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Detalles Bibliográficos
Autores principales: Shi, Chun-Yue, Ge, Chun-Hua, Liu, Qi-Tao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007344/
https://www.ncbi.nlm.nih.gov/pubmed/21588124
http://dx.doi.org/10.1107/S1600536810025511
Descripción
Sumario:In the title compound, [Ag(C(12)H(9)ClN(2)O)(2)]NO(3), two N atoms from two pyridine rings of two N-(4-chloro­phen­yl)pyridine-3-carboxamide ligands coordinate to the Ag(I) atom, forming a nearly linear geometry with an N—Ag—N angle of 173.41 (7)°. The crystal structure is stabilized by N—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.5469 (16) Å] between the pyridyl and benzene rings. The shortest Ag⋯Ag distance is 3.2574 (5) Å.

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