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Bis[N-(4-chloro­phen­yl)pyridine-3-carboxamide]­silver(I) nitrate

In the title compound, [Ag(C(12)H(9)ClN(2)O)(2)]NO(3), two N atoms from two pyridine rings of two N-(4-chloro­phen­yl)pyridine-3-carboxamide ligands coordinate to the Ag(I) atom, forming a nearly linear geometry with an N—Ag—N angle of 173.41 (7)°. The crystal structure is stabilized by N—H⋯O, C—H⋯O...

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Detalles Bibliográficos
Autores principales: Shi, Chun-Yue, Ge, Chun-Hua, Liu, Qi-Tao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007344/
https://www.ncbi.nlm.nih.gov/pubmed/21588124
http://dx.doi.org/10.1107/S1600536810025511
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author Shi, Chun-Yue
Ge, Chun-Hua
Liu, Qi-Tao
author_facet Shi, Chun-Yue
Ge, Chun-Hua
Liu, Qi-Tao
author_sort Shi, Chun-Yue
collection PubMed
description In the title compound, [Ag(C(12)H(9)ClN(2)O)(2)]NO(3), two N atoms from two pyridine rings of two N-(4-chloro­phen­yl)pyridine-3-carboxamide ligands coordinate to the Ag(I) atom, forming a nearly linear geometry with an N—Ag—N angle of 173.41 (7)°. The crystal structure is stabilized by N—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.5469 (16) Å] between the pyridyl and benzene rings. The shortest Ag⋯Ag distance is 3.2574 (5) Å.
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spelling pubmed-30073442010-12-30 Bis[N-(4-chloro­phen­yl)pyridine-3-carboxamide]­silver(I) nitrate Shi, Chun-Yue Ge, Chun-Hua Liu, Qi-Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(C(12)H(9)ClN(2)O)(2)]NO(3), two N atoms from two pyridine rings of two N-(4-chloro­phen­yl)pyridine-3-carboxamide ligands coordinate to the Ag(I) atom, forming a nearly linear geometry with an N—Ag—N angle of 173.41 (7)°. The crystal structure is stabilized by N—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.5469 (16) Å] between the pyridyl and benzene rings. The shortest Ag⋯Ag distance is 3.2574 (5) Å. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007344/ /pubmed/21588124 http://dx.doi.org/10.1107/S1600536810025511 Text en © Shi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Chun-Yue
Ge, Chun-Hua
Liu, Qi-Tao
Bis[N-(4-chloro­phen­yl)pyridine-3-carboxamide]­silver(I) nitrate
title Bis[N-(4-chloro­phen­yl)pyridine-3-carboxamide]­silver(I) nitrate
title_full Bis[N-(4-chloro­phen­yl)pyridine-3-carboxamide]­silver(I) nitrate
title_fullStr Bis[N-(4-chloro­phen­yl)pyridine-3-carboxamide]­silver(I) nitrate
title_full_unstemmed Bis[N-(4-chloro­phen­yl)pyridine-3-carboxamide]­silver(I) nitrate
title_short Bis[N-(4-chloro­phen­yl)pyridine-3-carboxamide]­silver(I) nitrate
title_sort bis[n-(4-chloro­phen­yl)pyridine-3-carboxamide]­silver(i) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007344/
https://www.ncbi.nlm.nih.gov/pubmed/21588124
http://dx.doi.org/10.1107/S1600536810025511
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