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Bis[N-(4-chlorophenyl)pyridine-3-carboxamide]silver(I) nitrate
In the title compound, [Ag(C(12)H(9)ClN(2)O)(2)]NO(3), two N atoms from two pyridine rings of two N-(4-chlorophenyl)pyridine-3-carboxamide ligands coordinate to the Ag(I) atom, forming a nearly linear geometry with an N—Ag—N angle of 173.41 (7)°. The crystal structure is stabilized by N—H⋯O, C—H⋯O...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007344/ https://www.ncbi.nlm.nih.gov/pubmed/21588124 http://dx.doi.org/10.1107/S1600536810025511 |
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author | Shi, Chun-Yue Ge, Chun-Hua Liu, Qi-Tao |
author_facet | Shi, Chun-Yue Ge, Chun-Hua Liu, Qi-Tao |
author_sort | Shi, Chun-Yue |
collection | PubMed |
description | In the title compound, [Ag(C(12)H(9)ClN(2)O)(2)]NO(3), two N atoms from two pyridine rings of two N-(4-chlorophenyl)pyridine-3-carboxamide ligands coordinate to the Ag(I) atom, forming a nearly linear geometry with an N—Ag—N angle of 173.41 (7)°. The crystal structure is stabilized by N—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 3.5469 (16) Å] between the pyridyl and benzene rings. The shortest Ag⋯Ag distance is 3.2574 (5) Å. |
format | Text |
id | pubmed-3007344 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30073442010-12-30 Bis[N-(4-chlorophenyl)pyridine-3-carboxamide]silver(I) nitrate Shi, Chun-Yue Ge, Chun-Hua Liu, Qi-Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(C(12)H(9)ClN(2)O)(2)]NO(3), two N atoms from two pyridine rings of two N-(4-chlorophenyl)pyridine-3-carboxamide ligands coordinate to the Ag(I) atom, forming a nearly linear geometry with an N—Ag—N angle of 173.41 (7)°. The crystal structure is stabilized by N—H⋯O, C—H⋯O and C—H⋯Cl hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 3.5469 (16) Å] between the pyridyl and benzene rings. The shortest Ag⋯Ag distance is 3.2574 (5) Å. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007344/ /pubmed/21588124 http://dx.doi.org/10.1107/S1600536810025511 Text en © Shi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shi, Chun-Yue Ge, Chun-Hua Liu, Qi-Tao Bis[N-(4-chlorophenyl)pyridine-3-carboxamide]silver(I) nitrate |
title | Bis[N-(4-chlorophenyl)pyridine-3-carboxamide]silver(I) nitrate |
title_full | Bis[N-(4-chlorophenyl)pyridine-3-carboxamide]silver(I) nitrate |
title_fullStr | Bis[N-(4-chlorophenyl)pyridine-3-carboxamide]silver(I) nitrate |
title_full_unstemmed | Bis[N-(4-chlorophenyl)pyridine-3-carboxamide]silver(I) nitrate |
title_short | Bis[N-(4-chlorophenyl)pyridine-3-carboxamide]silver(I) nitrate |
title_sort | bis[n-(4-chlorophenyl)pyridine-3-carboxamide]silver(i) nitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007344/ https://www.ncbi.nlm.nih.gov/pubmed/21588124 http://dx.doi.org/10.1107/S1600536810025511 |
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