Cargando…
4,4′-Ethylenedipyridinium bis(3,4,5-trihydroxybenzoate) sesquihydrate
The asymmetric unit of the title compound, C(12)H(14)N(2) (2+)·2C(7)H(5)O(5) (−)·1.5H(2)O, contains two 4,4′-ethylenedipyridinium cations, four gallate anions and three water molecules. In the 4,4′-ethylenedipyridinium cations, the dihedral angles between the pyridinium rings are 4.3 (3) and 18.6...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007348/ https://www.ncbi.nlm.nih.gov/pubmed/21588362 http://dx.doi.org/10.1107/S1600536810027169 |
Sumario: | The asymmetric unit of the title compound, C(12)H(14)N(2) (2+)·2C(7)H(5)O(5) (−)·1.5H(2)O, contains two 4,4′-ethylenedipyridinium cations, four gallate anions and three water molecules. In the 4,4′-ethylenedipyridinium cations, the dihedral angles between the pyridinium rings are 4.3 (3) and 18.6 (3)°. Extensive classical N—H⋯O and O—H⋯O hydrogen bonding and weak C—H⋯O hydrogen bonding and C—H⋯π interactions are present in the crystal structure. π–π stacking is also observed, the centroid–centroid separations between the benzene and pyridine rings being 3.611 (3), 3.448 (3) and 3.536 (3) Å. |
---|