catena-Poly[[triphenyl­tin(IV)]-μ-2-(cyclo­hexyl­amino­carbon­yl)benzoato-κ(2) O (1):O (2)]

In the title polymeric complex, [Sn(C(6)H(5))(3)(C(14)H(16)NO(3))](n), adjacent triphenyl­tin cations are bridged by the N-cyclo­hexyl­phthalamate anion through the carboxyl­ate and carbonyl O atoms, forming a helical chain running along the b axis. The amide N atom is a hydrogen-bond donor to the u...

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Detalles Bibliográficos
Autores principales: Imtiaz-ud-Din, Raqiqt-ul-Rasool, Bhatti, Moazzam H., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007350/
https://www.ncbi.nlm.nih.gov/pubmed/21588163
http://dx.doi.org/10.1107/S1600536810026978
Descripción
Sumario:In the title polymeric complex, [Sn(C(6)H(5))(3)(C(14)H(16)NO(3))](n), adjacent triphenyl­tin cations are bridged by the N-cyclo­hexyl­phthalamate anion through the carboxyl­ate and carbonyl O atoms, forming a helical chain running along the b axis. The amide N atom is a hydrogen-bond donor to the uncoordinated carboxyl­ate O atom. The geometry at the five-coordinate Sn atom is trans-C(3)SnO(2) trigonal-bipyramidal.

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