catena-Poly[[triphenyl­tin(IV)]-μ-2-(cyclo­hexyl­amino­carbon­yl)benzoato-κ(2) O (1):O (2)]

In the title polymeric complex, [Sn(C(6)H(5))(3)(C(14)H(16)NO(3))](n), adjacent triphenyl­tin cations are bridged by the N-cyclo­hexyl­phthalamate anion through the carboxyl­ate and carbonyl O atoms, forming a helical chain running along the b axis. The amide N atom is a hydrogen-bond donor to the u...

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Detalles Bibliográficos
Autores principales: Imtiaz-ud-Din, Raqiqt-ul-Rasool, Bhatti, Moazzam H., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007350/
https://www.ncbi.nlm.nih.gov/pubmed/21588163
http://dx.doi.org/10.1107/S1600536810026978
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author Imtiaz-ud-Din,
Raqiqt-ul-Rasool,
Bhatti, Moazzam H.
Ng, Seik Weng
author_facet Imtiaz-ud-Din,
Raqiqt-ul-Rasool,
Bhatti, Moazzam H.
Ng, Seik Weng
author_sort Imtiaz-ud-Din,
collection PubMed
description In the title polymeric complex, [Sn(C(6)H(5))(3)(C(14)H(16)NO(3))](n), adjacent triphenyl­tin cations are bridged by the N-cyclo­hexyl­phthalamate anion through the carboxyl­ate and carbonyl O atoms, forming a helical chain running along the b axis. The amide N atom is a hydrogen-bond donor to the uncoordinated carboxyl­ate O atom. The geometry at the five-coordinate Sn atom is trans-C(3)SnO(2) trigonal-bipyramidal.
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spelling pubmed-30073502010-12-30 catena-Poly[[triphenyl­tin(IV)]-μ-2-(cyclo­hexyl­amino­carbon­yl)benzoato-κ(2) O (1):O (2)] Imtiaz-ud-Din, Raqiqt-ul-Rasool, Bhatti, Moazzam H. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric complex, [Sn(C(6)H(5))(3)(C(14)H(16)NO(3))](n), adjacent triphenyl­tin cations are bridged by the N-cyclo­hexyl­phthalamate anion through the carboxyl­ate and carbonyl O atoms, forming a helical chain running along the b axis. The amide N atom is a hydrogen-bond donor to the uncoordinated carboxyl­ate O atom. The geometry at the five-coordinate Sn atom is trans-C(3)SnO(2) trigonal-bipyramidal. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007350/ /pubmed/21588163 http://dx.doi.org/10.1107/S1600536810026978 Text en © Imtiaz-ud-Din et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Imtiaz-ud-Din,
Raqiqt-ul-Rasool,
Bhatti, Moazzam H.
Ng, Seik Weng
catena-Poly[[triphenyl­tin(IV)]-μ-2-(cyclo­hexyl­amino­carbon­yl)benzoato-κ(2) O (1):O (2)]
title catena-Poly[[triphenyl­tin(IV)]-μ-2-(cyclo­hexyl­amino­carbon­yl)benzoato-κ(2) O (1):O (2)]
title_full catena-Poly[[triphenyl­tin(IV)]-μ-2-(cyclo­hexyl­amino­carbon­yl)benzoato-κ(2) O (1):O (2)]
title_fullStr catena-Poly[[triphenyl­tin(IV)]-μ-2-(cyclo­hexyl­amino­carbon­yl)benzoato-κ(2) O (1):O (2)]
title_full_unstemmed catena-Poly[[triphenyl­tin(IV)]-μ-2-(cyclo­hexyl­amino­carbon­yl)benzoato-κ(2) O (1):O (2)]
title_short catena-Poly[[triphenyl­tin(IV)]-μ-2-(cyclo­hexyl­amino­carbon­yl)benzoato-κ(2) O (1):O (2)]
title_sort catena-poly[[triphenyl­tin(iv)]-μ-2-(cyclo­hexyl­amino­carbon­yl)benzoato-κ(2) o (1):o (2)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007350/
https://www.ncbi.nlm.nih.gov/pubmed/21588163
http://dx.doi.org/10.1107/S1600536810026978
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