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Ethyl 4-hydroxy-2,6-diphenyl-1-(2-thiomorpholinoacetyl)-1,2,5,6-tetrahydropyridine-3-carboxylate
In the title compound, C(26)H(30)N(2)O(4)S, the thiomorpholine ring adopts a chair conformation whereas the tetrahydropyridine ring is in a half-chair conformation. The dihedral angle between the two phenyl rings is 33.3 (2)°. A strong intramolecular O—H⋯O hydrogen bond generates an S(6) motif....
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007352/ https://www.ncbi.nlm.nih.gov/pubmed/21588298 http://dx.doi.org/10.1107/S1600536810026413 |
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author | Aridoss, G. Sundaramoorthy, S. Velmurugan, D. Park, K. S. Jeong, Y. T. |
author_facet | Aridoss, G. Sundaramoorthy, S. Velmurugan, D. Park, K. S. Jeong, Y. T. |
author_sort | Aridoss, G. |
collection | PubMed |
description | In the title compound, C(26)H(30)N(2)O(4)S, the thiomorpholine ring adopts a chair conformation whereas the tetrahydropyridine ring is in a half-chair conformation. The dihedral angle between the two phenyl rings is 33.3 (2)°. A strong intramolecular O—H⋯O hydrogen bond generates an S(6) motif. In the crystal, molecules are linked by intermolecular C—H⋯O hydrogen bonds, generating a ribbon-like structure propagating along the a axis. |
format | Text |
id | pubmed-3007352 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30073522010-12-30 Ethyl 4-hydroxy-2,6-diphenyl-1-(2-thiomorpholinoacetyl)-1,2,5,6-tetrahydropyridine-3-carboxylate Aridoss, G. Sundaramoorthy, S. Velmurugan, D. Park, K. S. Jeong, Y. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(30)N(2)O(4)S, the thiomorpholine ring adopts a chair conformation whereas the tetrahydropyridine ring is in a half-chair conformation. The dihedral angle between the two phenyl rings is 33.3 (2)°. A strong intramolecular O—H⋯O hydrogen bond generates an S(6) motif. In the crystal, molecules are linked by intermolecular C—H⋯O hydrogen bonds, generating a ribbon-like structure propagating along the a axis. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007352/ /pubmed/21588298 http://dx.doi.org/10.1107/S1600536810026413 Text en © Aridoss et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Aridoss, G. Sundaramoorthy, S. Velmurugan, D. Park, K. S. Jeong, Y. T. Ethyl 4-hydroxy-2,6-diphenyl-1-(2-thiomorpholinoacetyl)-1,2,5,6-tetrahydropyridine-3-carboxylate |
title | Ethyl 4-hydroxy-2,6-diphenyl-1-(2-thiomorpholinoacetyl)-1,2,5,6-tetrahydropyridine-3-carboxylate |
title_full | Ethyl 4-hydroxy-2,6-diphenyl-1-(2-thiomorpholinoacetyl)-1,2,5,6-tetrahydropyridine-3-carboxylate |
title_fullStr | Ethyl 4-hydroxy-2,6-diphenyl-1-(2-thiomorpholinoacetyl)-1,2,5,6-tetrahydropyridine-3-carboxylate |
title_full_unstemmed | Ethyl 4-hydroxy-2,6-diphenyl-1-(2-thiomorpholinoacetyl)-1,2,5,6-tetrahydropyridine-3-carboxylate |
title_short | Ethyl 4-hydroxy-2,6-diphenyl-1-(2-thiomorpholinoacetyl)-1,2,5,6-tetrahydropyridine-3-carboxylate |
title_sort | ethyl 4-hydroxy-2,6-diphenyl-1-(2-thiomorpholinoacetyl)-1,2,5,6-tetrahydropyridine-3-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007352/ https://www.ncbi.nlm.nih.gov/pubmed/21588298 http://dx.doi.org/10.1107/S1600536810026413 |
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