(E)-1,3-Bis(2,3,4,5,6-penta­fluoro­phen­yl)prop-2-en-1-one

In the title compound, C(15)H(2)F(10)O, the two perfluorinated arene rings are tilted at an angle of 66.08 (5)° with respect to each other. The olefinic double bond adopts an E configuration and the single bond between the olefinic and carbonyl double bonds has an s-trans conformation. The carbonyl...

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Detalles Bibliográficos
Autores principales: Schwarzer, Anke, Weber, Edwin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007353/
https://www.ncbi.nlm.nih.gov/pubmed/21588260
http://dx.doi.org/10.1107/S1600536810025675
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author Schwarzer, Anke
Weber, Edwin
author_facet Schwarzer, Anke
Weber, Edwin
author_sort Schwarzer, Anke
collection PubMed
description In the title compound, C(15)H(2)F(10)O, the two perfluorinated arene rings are tilted at an angle of 66.08 (5)° with respect to each other. The olefinic double bond adopts an E configuration and the single bond between the olefinic and carbonyl double bonds has an s-trans conformation. The carbonyl group is not in a coplanar alignment with respect to the neighbouring arene ring (0.963 Å from aryl plane) while being coplanar with regard to the olefinic double bond (0.0805 Å from olefinic bond). The crystal packing does not feature significant hydrogen-bond-type or stacking inter­actions.
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spelling pubmed-30073532010-12-30 (E)-1,3-Bis(2,3,4,5,6-penta­fluoro­phen­yl)prop-2-en-1-one Schwarzer, Anke Weber, Edwin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(2)F(10)O, the two perfluorinated arene rings are tilted at an angle of 66.08 (5)° with respect to each other. The olefinic double bond adopts an E configuration and the single bond between the olefinic and carbonyl double bonds has an s-trans conformation. The carbonyl group is not in a coplanar alignment with respect to the neighbouring arene ring (0.963 Å from aryl plane) while being coplanar with regard to the olefinic double bond (0.0805 Å from olefinic bond). The crystal packing does not feature significant hydrogen-bond-type or stacking inter­actions. International Union of Crystallography 2010-07-07 /pmc/articles/PMC3007353/ /pubmed/21588260 http://dx.doi.org/10.1107/S1600536810025675 Text en © Schwarzer and Weber 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Schwarzer, Anke
Weber, Edwin
(E)-1,3-Bis(2,3,4,5,6-penta­fluoro­phen­yl)prop-2-en-1-one
title (E)-1,3-Bis(2,3,4,5,6-penta­fluoro­phen­yl)prop-2-en-1-one
title_full (E)-1,3-Bis(2,3,4,5,6-penta­fluoro­phen­yl)prop-2-en-1-one
title_fullStr (E)-1,3-Bis(2,3,4,5,6-penta­fluoro­phen­yl)prop-2-en-1-one
title_full_unstemmed (E)-1,3-Bis(2,3,4,5,6-penta­fluoro­phen­yl)prop-2-en-1-one
title_short (E)-1,3-Bis(2,3,4,5,6-penta­fluoro­phen­yl)prop-2-en-1-one
title_sort (e)-1,3-bis(2,3,4,5,6-penta­fluoro­phen­yl)prop-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007353/
https://www.ncbi.nlm.nih.gov/pubmed/21588260
http://dx.doi.org/10.1107/S1600536810025675
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