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[μ-1,2-Bis(diphenylphosphino)ethane-κ(2) P:P′]bis{[1,2-bis(diphenylphosphino)ethane-κ(2) P,P′]cyanidocopper(I)} methanol disolvate
The title centrosymmetric complex, [Cu(2)(CN)(2)(C(26)H(24)P(2))(3)]·2CH(3)OH, consists of two five-membered [Cu(dppe)CN] rings [dppe is 1,2-bis(diphenylphosphino)ethane] bridged by one μ(2)-dppe ligand, and two methanol solvent molecules. The angles around the central metal atom indicate that ea...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007356/ https://www.ncbi.nlm.nih.gov/pubmed/21588106 http://dx.doi.org/10.1107/S1600536810029545 |
Sumario: | The title centrosymmetric complex, [Cu(2)(CN)(2)(C(26)H(24)P(2))(3)]·2CH(3)OH, consists of two five-membered [Cu(dppe)CN] rings [dppe is 1,2-bis(diphenylphosphino)ethane] bridged by one μ(2)-dppe ligand, and two methanol solvent molecules. The angles around the central metal atom indicate that each Cu(I) atom is located in the center of a distorted tetrahedron. The coordination sphere of each Cu(I) atom is formed by three P atoms from two dppe ligands, and one C atom from the cyanide ligand. The crystal structure is stabilized by O—H⋯N hydrogen bonds, which are formed by the O—H donor group from methanol and the N-atom acceptor from a cyanide ligand. |
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