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[μ-1,2-Bis(diphenyl­phosphino)ethane-κ(2) P:P′]bis­{[1,2-bis­(diphenyl­phosphino)ethane-κ(2) P,P′]cyanidocopper(I)} methanol disolvate

The title centrosymmetric complex, [Cu(2)(CN)(2)(C(26)H(24)P(2))(3)]·2CH(3)OH, consists of two five-membered [Cu(dppe)CN] rings [dppe is 1,2-bis­(diphenyl­phosphino)ethane] bridged by one μ(2)-dppe ligand, and two methanol solvent mol­ecules. The angles around the central metal atom indicate that ea...

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Detalles Bibliográficos
Autores principales: Wang, Rong, Xiao, Ye-Lan, Jin, Qiong-Hua, Zhang, Cun-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007356/
https://www.ncbi.nlm.nih.gov/pubmed/21588106
http://dx.doi.org/10.1107/S1600536810029545
Descripción
Sumario:The title centrosymmetric complex, [Cu(2)(CN)(2)(C(26)H(24)P(2))(3)]·2CH(3)OH, consists of two five-membered [Cu(dppe)CN] rings [dppe is 1,2-bis­(diphenyl­phosphino)ethane] bridged by one μ(2)-dppe ligand, and two methanol solvent mol­ecules. The angles around the central metal atom indicate that each Cu(I) atom is located in the center of a distorted tetra­hedron. The coordination sphere of each Cu(I) atom is formed by three P atoms from two dppe ligands, and one C atom from the cyanide ligand. The crystal structure is stabilized by O—H⋯N hydrogen bonds, which are formed by the O—H donor group from methanol and the N-atom acceptor from a cyanide ligand.