[μ-1,2-Bis(diphenyl­phosphino)ethane-κ(2) P:P′]bis­{[1,2-bis­(diphenyl­phosphino)ethane-κ(2) P,P′]cyanidocopper(I)} methanol disolvate

The title centrosymmetric complex, [Cu(2)(CN)(2)(C(26)H(24)P(2))(3)]·2CH(3)OH, consists of two five-membered [Cu(dppe)CN] rings [dppe is 1,2-bis­(diphenyl­phosphino)ethane] bridged by one μ(2)-dppe ligand, and two methanol solvent mol­ecules. The angles around the central metal atom indicate that ea...

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Detalles Bibliográficos
Autores principales: Wang, Rong, Xiao, Ye-Lan, Jin, Qiong-Hua, Zhang, Cun-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007356/
https://www.ncbi.nlm.nih.gov/pubmed/21588106
http://dx.doi.org/10.1107/S1600536810029545
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author Wang, Rong
Xiao, Ye-Lan
Jin, Qiong-Hua
Zhang, Cun-Lin
author_facet Wang, Rong
Xiao, Ye-Lan
Jin, Qiong-Hua
Zhang, Cun-Lin
author_sort Wang, Rong
collection PubMed
description The title centrosymmetric complex, [Cu(2)(CN)(2)(C(26)H(24)P(2))(3)]·2CH(3)OH, consists of two five-membered [Cu(dppe)CN] rings [dppe is 1,2-bis­(diphenyl­phosphino)ethane] bridged by one μ(2)-dppe ligand, and two methanol solvent mol­ecules. The angles around the central metal atom indicate that each Cu(I) atom is located in the center of a distorted tetra­hedron. The coordination sphere of each Cu(I) atom is formed by three P atoms from two dppe ligands, and one C atom from the cyanide ligand. The crystal structure is stabilized by O—H⋯N hydrogen bonds, which are formed by the O—H donor group from methanol and the N-atom acceptor from a cyanide ligand.
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spelling pubmed-30073562010-12-30 [μ-1,2-Bis(diphenyl­phosphino)ethane-κ(2) P:P′]bis­{[1,2-bis­(diphenyl­phosphino)ethane-κ(2) P,P′]cyanidocopper(I)} methanol disolvate Wang, Rong Xiao, Ye-Lan Jin, Qiong-Hua Zhang, Cun-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title centrosymmetric complex, [Cu(2)(CN)(2)(C(26)H(24)P(2))(3)]·2CH(3)OH, consists of two five-membered [Cu(dppe)CN] rings [dppe is 1,2-bis­(diphenyl­phosphino)ethane] bridged by one μ(2)-dppe ligand, and two methanol solvent mol­ecules. The angles around the central metal atom indicate that each Cu(I) atom is located in the center of a distorted tetra­hedron. The coordination sphere of each Cu(I) atom is formed by three P atoms from two dppe ligands, and one C atom from the cyanide ligand. The crystal structure is stabilized by O—H⋯N hydrogen bonds, which are formed by the O—H donor group from methanol and the N-atom acceptor from a cyanide ligand. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007356/ /pubmed/21588106 http://dx.doi.org/10.1107/S1600536810029545 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Rong
Xiao, Ye-Lan
Jin, Qiong-Hua
Zhang, Cun-Lin
[μ-1,2-Bis(diphenyl­phosphino)ethane-κ(2) P:P′]bis­{[1,2-bis­(diphenyl­phosphino)ethane-κ(2) P,P′]cyanidocopper(I)} methanol disolvate
title [μ-1,2-Bis(diphenyl­phosphino)ethane-κ(2) P:P′]bis­{[1,2-bis­(diphenyl­phosphino)ethane-κ(2) P,P′]cyanidocopper(I)} methanol disolvate
title_full [μ-1,2-Bis(diphenyl­phosphino)ethane-κ(2) P:P′]bis­{[1,2-bis­(diphenyl­phosphino)ethane-κ(2) P,P′]cyanidocopper(I)} methanol disolvate
title_fullStr [μ-1,2-Bis(diphenyl­phosphino)ethane-κ(2) P:P′]bis­{[1,2-bis­(diphenyl­phosphino)ethane-κ(2) P,P′]cyanidocopper(I)} methanol disolvate
title_full_unstemmed [μ-1,2-Bis(diphenyl­phosphino)ethane-κ(2) P:P′]bis­{[1,2-bis­(diphenyl­phosphino)ethane-κ(2) P,P′]cyanidocopper(I)} methanol disolvate
title_short [μ-1,2-Bis(diphenyl­phosphino)ethane-κ(2) P:P′]bis­{[1,2-bis­(diphenyl­phosphino)ethane-κ(2) P,P′]cyanidocopper(I)} methanol disolvate
title_sort [μ-1,2-bis(diphenyl­phosphino)ethane-κ(2) p:p′]bis­{[1,2-bis­(diphenyl­phosphino)ethane-κ(2) p,p′]cyanidocopper(i)} methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007356/
https://www.ncbi.nlm.nih.gov/pubmed/21588106
http://dx.doi.org/10.1107/S1600536810029545
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AT zhangcunlin m12bisdiphenylphosphinoethanek2ppbis12bisdiphenylphosphinoethanek2ppcyanidocopperimethanoldisolvate

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