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[rac-2-(1-Aminoethyl)phenyl-κ(2) C (1),N](ethylendiamine-κ(2) N,N′)palladium(II) 3-methylbenzoate monohydrate
In the title compound, [Pd(C(8)H(10)N)(C(2)H(8)N(2))](C(8)H(7)O(2))·H(2)O, the palladium ion is coordinated in a distorted square-planar fashion by the two N atoms from the chelating ethylenediamine group and by the N and a C atom of the deprotonated chiral amine. The resulting cationic complex, th...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007357/ https://www.ncbi.nlm.nih.gov/pubmed/21588200 http://dx.doi.org/10.1107/S1600536810028370 |
Sumario: | In the title compound, [Pd(C(8)H(10)N)(C(2)H(8)N(2))](C(8)H(7)O(2))·H(2)O, the palladium ion is coordinated in a distorted square-planar fashion by the two N atoms from the chelating ethylenediamine group and by the N and a C atom of the deprotonated chiral amine. The resulting cationic complex, the 3-methylbenzoate anion and the hydrate water molecule are interconnected by N—H⋯O and O—H⋯O hydrogen bonds. |
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