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[rac-2-(1-Aminoethyl)phenyl-κ(2) C (1),N](ethylendiamine-κ(2) N,N′)palladium(II) 3-methylbenzoate monohydrate
In the title compound, [Pd(C(8)H(10)N)(C(2)H(8)N(2))](C(8)H(7)O(2))·H(2)O, the palladium ion is coordinated in a distorted square-planar fashion by the two N atoms from the chelating ethylenediamine group and by the N and a C atom of the deprotonated chiral amine. The resulting cationic complex, th...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007357/ https://www.ncbi.nlm.nih.gov/pubmed/21588200 http://dx.doi.org/10.1107/S1600536810028370 |
| _version_ | 1782194337525792768 |
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| author | Şerb, Mihaela-Diana Kalf, Irmgard Englert, Ulli |
| author_facet | Şerb, Mihaela-Diana Kalf, Irmgard Englert, Ulli |
| author_sort | Şerb, Mihaela-Diana |
| collection | PubMed |
| description | In the title compound, [Pd(C(8)H(10)N)(C(2)H(8)N(2))](C(8)H(7)O(2))·H(2)O, the palladium ion is coordinated in a distorted square-planar fashion by the two N atoms from the chelating ethylenediamine group and by the N and a C atom of the deprotonated chiral amine. The resulting cationic complex, the 3-methylbenzoate anion and the hydrate water molecule are interconnected by N—H⋯O and O—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-3007357 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30073572010-12-30 [rac-2-(1-Aminoethyl)phenyl-κ(2) C (1),N](ethylendiamine-κ(2) N,N′)palladium(II) 3-methylbenzoate monohydrate Şerb, Mihaela-Diana Kalf, Irmgard Englert, Ulli Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(8)H(10)N)(C(2)H(8)N(2))](C(8)H(7)O(2))·H(2)O, the palladium ion is coordinated in a distorted square-planar fashion by the two N atoms from the chelating ethylenediamine group and by the N and a C atom of the deprotonated chiral amine. The resulting cationic complex, the 3-methylbenzoate anion and the hydrate water molecule are interconnected by N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007357/ /pubmed/21588200 http://dx.doi.org/10.1107/S1600536810028370 Text en © Şerb et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Şerb, Mihaela-Diana Kalf, Irmgard Englert, Ulli [rac-2-(1-Aminoethyl)phenyl-κ(2) C (1),N](ethylendiamine-κ(2) N,N′)palladium(II) 3-methylbenzoate monohydrate |
| title | [rac-2-(1-Aminoethyl)phenyl-κ(2)
C
(1),N](ethylendiamine-κ(2)
N,N′)palladium(II) 3-methylbenzoate monohydrate |
| title_full | [rac-2-(1-Aminoethyl)phenyl-κ(2)
C
(1),N](ethylendiamine-κ(2)
N,N′)palladium(II) 3-methylbenzoate monohydrate |
| title_fullStr | [rac-2-(1-Aminoethyl)phenyl-κ(2)
C
(1),N](ethylendiamine-κ(2)
N,N′)palladium(II) 3-methylbenzoate monohydrate |
| title_full_unstemmed | [rac-2-(1-Aminoethyl)phenyl-κ(2)
C
(1),N](ethylendiamine-κ(2)
N,N′)palladium(II) 3-methylbenzoate monohydrate |
| title_short | [rac-2-(1-Aminoethyl)phenyl-κ(2)
C
(1),N](ethylendiamine-κ(2)
N,N′)palladium(II) 3-methylbenzoate monohydrate |
| title_sort | [rac-2-(1-aminoethyl)phenyl-κ(2)
c
(1),n](ethylendiamine-κ(2)
n,n′)palladium(ii) 3-methylbenzoate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007357/ https://www.ncbi.nlm.nih.gov/pubmed/21588200 http://dx.doi.org/10.1107/S1600536810028370 |
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