(Methanol-κO)(perchlorato-κO)bis­(triphenyl­phosphine-κP)silver(I)

In the title complex, [Ag(ClO(4))(CH(3)OH)(C(18)H(15)P)(2)], the angles around the central Ag(+) ion indicate that it is in a distorted tetrahedral coordination. The coordination sphere of silver is formed by two P atoms of two triphenyl­phosphine ligands, one O atom of a perchlorate anion and one O...

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Detalles Bibliográficos
Autores principales: Cui, Li-Na, Jin, Qiong-Hua, Hu, Ke-Yi, Zhang, Cun-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007358/
https://www.ncbi.nlm.nih.gov/pubmed/21588194
http://dx.doi.org/10.1107/S160053681002814X
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author Cui, Li-Na
Jin, Qiong-Hua
Hu, Ke-Yi
Zhang, Cun-Lin
author_facet Cui, Li-Na
Jin, Qiong-Hua
Hu, Ke-Yi
Zhang, Cun-Lin
author_sort Cui, Li-Na
collection PubMed
description In the title complex, [Ag(ClO(4))(CH(3)OH)(C(18)H(15)P)(2)], the angles around the central Ag(+) ion indicate that it is in a distorted tetrahedral coordination. The coordination sphere of silver is formed by two P atoms of two triphenyl­phosphine ligands, one O atom of a perchlorate anion and one O atom of a methanol mol­ecule. The crystal structure is stablized by a bifurcated inter­molecular O—H⋯O hydrogen bond, involving the O—H donor from methanol and two acceptor O atoms from the perchlorate anion, so forming a zigzag chain propagating in [010].
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spelling pubmed-30073582010-12-30 (Methanol-κO)(perchlorato-κO)bis­(triphenyl­phosphine-κP)silver(I) Cui, Li-Na Jin, Qiong-Hua Hu, Ke-Yi Zhang, Cun-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ag(ClO(4))(CH(3)OH)(C(18)H(15)P)(2)], the angles around the central Ag(+) ion indicate that it is in a distorted tetrahedral coordination. The coordination sphere of silver is formed by two P atoms of two triphenyl­phosphine ligands, one O atom of a perchlorate anion and one O atom of a methanol mol­ecule. The crystal structure is stablized by a bifurcated inter­molecular O—H⋯O hydrogen bond, involving the O—H donor from methanol and two acceptor O atoms from the perchlorate anion, so forming a zigzag chain propagating in [010]. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007358/ /pubmed/21588194 http://dx.doi.org/10.1107/S160053681002814X Text en © Cui et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cui, Li-Na
Jin, Qiong-Hua
Hu, Ke-Yi
Zhang, Cun-Lin
(Methanol-κO)(perchlorato-κO)bis­(triphenyl­phosphine-κP)silver(I)
title (Methanol-κO)(perchlorato-κO)bis­(triphenyl­phosphine-κP)silver(I)
title_full (Methanol-κO)(perchlorato-κO)bis­(triphenyl­phosphine-κP)silver(I)
title_fullStr (Methanol-κO)(perchlorato-κO)bis­(triphenyl­phosphine-κP)silver(I)
title_full_unstemmed (Methanol-κO)(perchlorato-κO)bis­(triphenyl­phosphine-κP)silver(I)
title_short (Methanol-κO)(perchlorato-κO)bis­(triphenyl­phosphine-κP)silver(I)
title_sort (methanol-κo)(perchlorato-κo)bis­(triphenyl­phosphine-κp)silver(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007358/
https://www.ncbi.nlm.nih.gov/pubmed/21588194
http://dx.doi.org/10.1107/S160053681002814X
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AT jinqionghua methanolkoperchloratokobistriphenylphosphinekpsilveri
AT hukeyi methanolkoperchloratokobistriphenylphosphinekpsilveri
AT zhangcunlin methanolkoperchloratokobistriphenylphosphinekpsilveri

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