[rac-2-(1-Amino­eth­yl)phenyl-κ(2) C (1),N](ethyl­endiamine-κ(2) N,N′)palladium(II) 3,5-dimethyl­benzoate

In the title compound, [Pd(C(8)H(10)N)(C(2)H(8)N(2))](C(9)H(9)O(2)), the palladium ion is coordinated in a distorted square-planar fashion by the two N atoms from the chelating ethyl­enediamine group and by the N and a C atom of the deprotonated chiral amine. The resulting cationic complex and the 3...

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Detalles Bibliográficos
Autores principales: Şerb, Mihaela-Diana, Kalf, Irmgard, Englert, Ulli
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007359/
https://www.ncbi.nlm.nih.gov/pubmed/21588201
http://dx.doi.org/10.1107/S1600536810028369
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author Şerb, Mihaela-Diana
Kalf, Irmgard
Englert, Ulli
author_facet Şerb, Mihaela-Diana
Kalf, Irmgard
Englert, Ulli
author_sort Şerb, Mihaela-Diana
collection PubMed
description In the title compound, [Pd(C(8)H(10)N)(C(2)H(8)N(2))](C(9)H(9)O(2)), the palladium ion is coordinated in a distorted square-planar fashion by the two N atoms from the chelating ethyl­enediamine group and by the N and a C atom of the deprotonated chiral amine. The resulting cationic complex and the 3,5-dimethyl­benzoate anion are inter­connected by N—H⋯O hydrogen bonds.
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spelling pubmed-30073592010-12-30 [rac-2-(1-Amino­eth­yl)phenyl-κ(2) C (1),N](ethyl­endiamine-κ(2) N,N′)palladium(II) 3,5-dimethyl­benzoate Şerb, Mihaela-Diana Kalf, Irmgard Englert, Ulli Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(8)H(10)N)(C(2)H(8)N(2))](C(9)H(9)O(2)), the palladium ion is coordinated in a distorted square-planar fashion by the two N atoms from the chelating ethyl­enediamine group and by the N and a C atom of the deprotonated chiral amine. The resulting cationic complex and the 3,5-dimethyl­benzoate anion are inter­connected by N—H⋯O hydrogen bonds. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007359/ /pubmed/21588201 http://dx.doi.org/10.1107/S1600536810028369 Text en © Şerb et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Şerb, Mihaela-Diana
Kalf, Irmgard
Englert, Ulli
[rac-2-(1-Amino­eth­yl)phenyl-κ(2) C (1),N](ethyl­endiamine-κ(2) N,N′)palladium(II) 3,5-dimethyl­benzoate
title [rac-2-(1-Amino­eth­yl)phenyl-κ(2) C (1),N](ethyl­endiamine-κ(2) N,N′)palladium(II) 3,5-dimethyl­benzoate
title_full [rac-2-(1-Amino­eth­yl)phenyl-κ(2) C (1),N](ethyl­endiamine-κ(2) N,N′)palladium(II) 3,5-dimethyl­benzoate
title_fullStr [rac-2-(1-Amino­eth­yl)phenyl-κ(2) C (1),N](ethyl­endiamine-κ(2) N,N′)palladium(II) 3,5-dimethyl­benzoate
title_full_unstemmed [rac-2-(1-Amino­eth­yl)phenyl-κ(2) C (1),N](ethyl­endiamine-κ(2) N,N′)palladium(II) 3,5-dimethyl­benzoate
title_short [rac-2-(1-Amino­eth­yl)phenyl-κ(2) C (1),N](ethyl­endiamine-κ(2) N,N′)palladium(II) 3,5-dimethyl­benzoate
title_sort [rac-2-(1-amino­eth­yl)phenyl-κ(2) c (1),n](ethyl­endiamine-κ(2) n,n′)palladium(ii) 3,5-dimethyl­benzoate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007359/
https://www.ncbi.nlm.nih.gov/pubmed/21588201
http://dx.doi.org/10.1107/S1600536810028369
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AT kalfirmgard rac21aminoethylphenylk2c1nethylendiaminek2nnpalladiumii35dimethylbenzoate
AT englertulli rac21aminoethylphenylk2c1nethylendiaminek2nnpalladiumii35dimethylbenzoate

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