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N-(6-{2-[6-(2,2-Dimethyl­propanamido)-2-pyrid­yl]eth­yl}-2-pyrid­yl)-2,2-dimethyl­propanamide

The title compound, C(22)H(30)N(4)O(2), lies about a crystallographic inversion center. The whole mol­ecule is disordered over two positions with a refined occupancy ratio of 0.636 (10):0.364 (10). The pyridine rings are approximately planar, with maximum deviations of 0.033 (10) and 0.063 (17) Å fo...

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Autores principales: Fun, Hoong-Kun, Loh, Wan-Sin, Das, Nirmal Kumar, Sen, Debabrata, Goswami, Shyamaprosad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007361/
https://www.ncbi.nlm.nih.gov/pubmed/21588283
http://dx.doi.org/10.1107/S1600536810023068
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author Fun, Hoong-Kun
Loh, Wan-Sin
Das, Nirmal Kumar
Sen, Debabrata
Goswami, Shyamaprosad
author_facet Fun, Hoong-Kun
Loh, Wan-Sin
Das, Nirmal Kumar
Sen, Debabrata
Goswami, Shyamaprosad
author_sort Fun, Hoong-Kun
collection PubMed
description The title compound, C(22)H(30)N(4)O(2), lies about a crystallographic inversion center. The whole mol­ecule is disordered over two positions with a refined occupancy ratio of 0.636 (10):0.364 (10). The pyridine rings are approximately planar, with maximum deviations of 0.033 (10) and 0.063 (17) Å for the major and minor components, respectively. The mean planes of the pyridine rings form dihedral angles of 17 (2)° in the major component and 18 (2)° in the minor component with the respective formamide groups attached to them. In the crystal packing, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into two-dimensional networks parallel to the ab plane.
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spelling pubmed-30073612010-12-30 N-(6-{2-[6-(2,2-Dimethyl­propanamido)-2-pyrid­yl]eth­yl}-2-pyrid­yl)-2,2-dimethyl­propanamide Fun, Hoong-Kun Loh, Wan-Sin Das, Nirmal Kumar Sen, Debabrata Goswami, Shyamaprosad Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(30)N(4)O(2), lies about a crystallographic inversion center. The whole mol­ecule is disordered over two positions with a refined occupancy ratio of 0.636 (10):0.364 (10). The pyridine rings are approximately planar, with maximum deviations of 0.033 (10) and 0.063 (17) Å for the major and minor components, respectively. The mean planes of the pyridine rings form dihedral angles of 17 (2)° in the major component and 18 (2)° in the minor component with the respective formamide groups attached to them. In the crystal packing, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into two-dimensional networks parallel to the ab plane. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007361/ /pubmed/21588283 http://dx.doi.org/10.1107/S1600536810023068 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Loh, Wan-Sin
Das, Nirmal Kumar
Sen, Debabrata
Goswami, Shyamaprosad
N-(6-{2-[6-(2,2-Dimethyl­propanamido)-2-pyrid­yl]eth­yl}-2-pyrid­yl)-2,2-dimethyl­propanamide
title N-(6-{2-[6-(2,2-Dimethyl­propanamido)-2-pyrid­yl]eth­yl}-2-pyrid­yl)-2,2-dimethyl­propanamide
title_full N-(6-{2-[6-(2,2-Dimethyl­propanamido)-2-pyrid­yl]eth­yl}-2-pyrid­yl)-2,2-dimethyl­propanamide
title_fullStr N-(6-{2-[6-(2,2-Dimethyl­propanamido)-2-pyrid­yl]eth­yl}-2-pyrid­yl)-2,2-dimethyl­propanamide
title_full_unstemmed N-(6-{2-[6-(2,2-Dimethyl­propanamido)-2-pyrid­yl]eth­yl}-2-pyrid­yl)-2,2-dimethyl­propanamide
title_short N-(6-{2-[6-(2,2-Dimethyl­propanamido)-2-pyrid­yl]eth­yl}-2-pyrid­yl)-2,2-dimethyl­propanamide
title_sort n-(6-{2-[6-(2,2-dimethyl­propanamido)-2-pyrid­yl]eth­yl}-2-pyrid­yl)-2,2-dimethyl­propanamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007361/
https://www.ncbi.nlm.nih.gov/pubmed/21588283
http://dx.doi.org/10.1107/S1600536810023068
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