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Bis(2,2′-bi-1H-imidazole)­copper(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide)

In the title compound, [Cu(C(6)H(6)N(4))(2)](C(9)H(5)N(4)O)(2), the Cu(2+) ion (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole (H(2)biim) ligands, generating a square-planar CuN(4) geometry. The dihedral angle between the aromatic rings in the ligand is 0.70 (...

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Detalles Bibliográficos
Autores principales: Gaamoune, Bachir, Setifi, Zouaoui, Beghidja, Adel, El-Ghozzi, Malika, Setifi, Fatima, Avignant, Daniel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007362/
https://www.ncbi.nlm.nih.gov/pubmed/21588113
http://dx.doi.org/10.1107/S1600536810029752
Descripción
Sumario:In the title compound, [Cu(C(6)H(6)N(4))(2)](C(9)H(5)N(4)O)(2), the Cu(2+) ion (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole (H(2)biim) ligands, generating a square-planar CuN(4) geometry. The dihedral angle between the aromatic rings in the ligand is 0.70 (9)°. In the polynitrile 1,1,3,3-tetra­cyano-2-eth­oxy­propenide (tcnoet) anion, the C—N, C—C and C—O bond lengths indicate extensive electronic delocalization. An alternative description for the metal-ion geometry is an extremely distorted CuN(6) octa­hedron, with two N-bonded tcnoet anions completing the coordination. In the crystal, the components are linked by N—H⋯N and C—H⋯N inter­actions.