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Bis(2,2′-bi-1H-imidazole)copper(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide)
In the title compound, [Cu(C(6)H(6)N(4))(2)](C(9)H(5)N(4)O)(2), the Cu(2+) ion (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole (H(2)biim) ligands, generating a square-planar CuN(4) geometry. The dihedral angle between the aromatic rings in the ligand is 0.70 (...
Autores principales: | , , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007362/ https://www.ncbi.nlm.nih.gov/pubmed/21588113 http://dx.doi.org/10.1107/S1600536810029752 |
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author | Gaamoune, Bachir Setifi, Zouaoui Beghidja, Adel El-Ghozzi, Malika Setifi, Fatima Avignant, Daniel |
author_facet | Gaamoune, Bachir Setifi, Zouaoui Beghidja, Adel El-Ghozzi, Malika Setifi, Fatima Avignant, Daniel |
author_sort | Gaamoune, Bachir |
collection | PubMed |
description | In the title compound, [Cu(C(6)H(6)N(4))(2)](C(9)H(5)N(4)O)(2), the Cu(2+) ion (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole (H(2)biim) ligands, generating a square-planar CuN(4) geometry. The dihedral angle between the aromatic rings in the ligand is 0.70 (9)°. In the polynitrile 1,1,3,3-tetracyano-2-ethoxypropenide (tcnoet) anion, the C—N, C—C and C—O bond lengths indicate extensive electronic delocalization. An alternative description for the metal-ion geometry is an extremely distorted CuN(6) octahedron, with two N-bonded tcnoet anions completing the coordination. In the crystal, the components are linked by N—H⋯N and C—H⋯N interactions. |
format | Text |
id | pubmed-3007362 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30073622010-12-30 Bis(2,2′-bi-1H-imidazole)copper(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) Gaamoune, Bachir Setifi, Zouaoui Beghidja, Adel El-Ghozzi, Malika Setifi, Fatima Avignant, Daniel Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(6)H(6)N(4))(2)](C(9)H(5)N(4)O)(2), the Cu(2+) ion (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole (H(2)biim) ligands, generating a square-planar CuN(4) geometry. The dihedral angle between the aromatic rings in the ligand is 0.70 (9)°. In the polynitrile 1,1,3,3-tetracyano-2-ethoxypropenide (tcnoet) anion, the C—N, C—C and C—O bond lengths indicate extensive electronic delocalization. An alternative description for the metal-ion geometry is an extremely distorted CuN(6) octahedron, with two N-bonded tcnoet anions completing the coordination. In the crystal, the components are linked by N—H⋯N and C—H⋯N interactions. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007362/ /pubmed/21588113 http://dx.doi.org/10.1107/S1600536810029752 Text en © Gaamoune et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gaamoune, Bachir Setifi, Zouaoui Beghidja, Adel El-Ghozzi, Malika Setifi, Fatima Avignant, Daniel Bis(2,2′-bi-1H-imidazole)copper(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) |
title | Bis(2,2′-bi-1H-imidazole)copper(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) |
title_full | Bis(2,2′-bi-1H-imidazole)copper(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) |
title_fullStr | Bis(2,2′-bi-1H-imidazole)copper(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) |
title_full_unstemmed | Bis(2,2′-bi-1H-imidazole)copper(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) |
title_short | Bis(2,2′-bi-1H-imidazole)copper(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide) |
title_sort | bis(2,2′-bi-1h-imidazole)copper(ii) bis(1,1,3,3-tetracyano-2-ethoxypropenide) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007362/ https://www.ncbi.nlm.nih.gov/pubmed/21588113 http://dx.doi.org/10.1107/S1600536810029752 |
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