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Bis(2,2′-bi-1H-imidazole)­copper(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide)

In the title compound, [Cu(C(6)H(6)N(4))(2)](C(9)H(5)N(4)O)(2), the Cu(2+) ion (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole (H(2)biim) ligands, generating a square-planar CuN(4) geometry. The dihedral angle between the aromatic rings in the ligand is 0.70 (...

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Autores principales: Gaamoune, Bachir, Setifi, Zouaoui, Beghidja, Adel, El-Ghozzi, Malika, Setifi, Fatima, Avignant, Daniel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007362/
https://www.ncbi.nlm.nih.gov/pubmed/21588113
http://dx.doi.org/10.1107/S1600536810029752
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author Gaamoune, Bachir
Setifi, Zouaoui
Beghidja, Adel
El-Ghozzi, Malika
Setifi, Fatima
Avignant, Daniel
author_facet Gaamoune, Bachir
Setifi, Zouaoui
Beghidja, Adel
El-Ghozzi, Malika
Setifi, Fatima
Avignant, Daniel
author_sort Gaamoune, Bachir
collection PubMed
description In the title compound, [Cu(C(6)H(6)N(4))(2)](C(9)H(5)N(4)O)(2), the Cu(2+) ion (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole (H(2)biim) ligands, generating a square-planar CuN(4) geometry. The dihedral angle between the aromatic rings in the ligand is 0.70 (9)°. In the polynitrile 1,1,3,3-tetra­cyano-2-eth­oxy­propenide (tcnoet) anion, the C—N, C—C and C—O bond lengths indicate extensive electronic delocalization. An alternative description for the metal-ion geometry is an extremely distorted CuN(6) octa­hedron, with two N-bonded tcnoet anions completing the coordination. In the crystal, the components are linked by N—H⋯N and C—H⋯N inter­actions.
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spelling pubmed-30073622010-12-30 Bis(2,2′-bi-1H-imidazole)­copper(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide) Gaamoune, Bachir Setifi, Zouaoui Beghidja, Adel El-Ghozzi, Malika Setifi, Fatima Avignant, Daniel Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(6)H(6)N(4))(2)](C(9)H(5)N(4)O)(2), the Cu(2+) ion (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole (H(2)biim) ligands, generating a square-planar CuN(4) geometry. The dihedral angle between the aromatic rings in the ligand is 0.70 (9)°. In the polynitrile 1,1,3,3-tetra­cyano-2-eth­oxy­propenide (tcnoet) anion, the C—N, C—C and C—O bond lengths indicate extensive electronic delocalization. An alternative description for the metal-ion geometry is an extremely distorted CuN(6) octa­hedron, with two N-bonded tcnoet anions completing the coordination. In the crystal, the components are linked by N—H⋯N and C—H⋯N inter­actions. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007362/ /pubmed/21588113 http://dx.doi.org/10.1107/S1600536810029752 Text en © Gaamoune et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gaamoune, Bachir
Setifi, Zouaoui
Beghidja, Adel
El-Ghozzi, Malika
Setifi, Fatima
Avignant, Daniel
Bis(2,2′-bi-1H-imidazole)­copper(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide)
title Bis(2,2′-bi-1H-imidazole)­copper(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide)
title_full Bis(2,2′-bi-1H-imidazole)­copper(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide)
title_fullStr Bis(2,2′-bi-1H-imidazole)­copper(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide)
title_full_unstemmed Bis(2,2′-bi-1H-imidazole)­copper(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide)
title_short Bis(2,2′-bi-1H-imidazole)­copper(II) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide)
title_sort bis(2,2′-bi-1h-imidazole)­copper(ii) bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenide)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007362/
https://www.ncbi.nlm.nih.gov/pubmed/21588113
http://dx.doi.org/10.1107/S1600536810029752
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