Tris(ethyl­enediamine)­nickel(II) 1H-pyrazole-3,5-dicarboxyl­ate 1.67-hydrate

The asymmetric unit of the title compound, [Ni(C(2)H(8)N(2))(3)](C(5)H(2)N(2)O(4))·1.67H(2)O, consists of three [Ni(en)(3)](2+) dications (en is ethyl­enediamine), three [(pzdc)(3)](2−) dianions (pzdc is pyrazole-3,5-dicarboxyl­ate) and five water mol­ecules. In each complex dication, the Ni(II) ato...

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Autores principales: Demirtaş, Güneş, Dege, Necmi, Yeşilel, Okan Zafer, Erer, Hakan, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007365/
https://www.ncbi.nlm.nih.gov/pubmed/21588159
http://dx.doi.org/10.1107/S1600536810027066
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author Demirtaş, Güneş
Dege, Necmi
Yeşilel, Okan Zafer
Erer, Hakan
Büyükgüngör, Orhan
author_facet Demirtaş, Güneş
Dege, Necmi
Yeşilel, Okan Zafer
Erer, Hakan
Büyükgüngör, Orhan
author_sort Demirtaş, Güneş
collection PubMed
description The asymmetric unit of the title compound, [Ni(C(2)H(8)N(2))(3)](C(5)H(2)N(2)O(4))·1.67H(2)O, consists of three [Ni(en)(3)](2+) dications (en is ethyl­enediamine), three [(pzdc)(3)](2−) dianions (pzdc is pyrazole-3,5-dicarboxyl­ate) and five water mol­ecules. In each complex dication, the Ni(II) atom is coordinated by six N atoms from three en ligands forming a distorted octa­hedral coordination geometry. In the crystal, the ions and water mol­ecules are linked into a three-dimensional framework by a large number of N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-30073652010-12-30 Tris(ethyl­enediamine)­nickel(II) 1H-pyrazole-3,5-dicarboxyl­ate 1.67-hydrate Demirtaş, Güneş Dege, Necmi Yeşilel, Okan Zafer Erer, Hakan Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ni(C(2)H(8)N(2))(3)](C(5)H(2)N(2)O(4))·1.67H(2)O, consists of three [Ni(en)(3)](2+) dications (en is ethyl­enediamine), three [(pzdc)(3)](2−) dianions (pzdc is pyrazole-3,5-dicarboxyl­ate) and five water mol­ecules. In each complex dication, the Ni(II) atom is coordinated by six N atoms from three en ligands forming a distorted octa­hedral coordination geometry. In the crystal, the ions and water mol­ecules are linked into a three-dimensional framework by a large number of N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007365/ /pubmed/21588159 http://dx.doi.org/10.1107/S1600536810027066 Text en © Demirtaş et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Demirtaş, Güneş
Dege, Necmi
Yeşilel, Okan Zafer
Erer, Hakan
Büyükgüngör, Orhan
Tris(ethyl­enediamine)­nickel(II) 1H-pyrazole-3,5-dicarboxyl­ate 1.67-hydrate
title Tris(ethyl­enediamine)­nickel(II) 1H-pyrazole-3,5-dicarboxyl­ate 1.67-hydrate
title_full Tris(ethyl­enediamine)­nickel(II) 1H-pyrazole-3,5-dicarboxyl­ate 1.67-hydrate
title_fullStr Tris(ethyl­enediamine)­nickel(II) 1H-pyrazole-3,5-dicarboxyl­ate 1.67-hydrate
title_full_unstemmed Tris(ethyl­enediamine)­nickel(II) 1H-pyrazole-3,5-dicarboxyl­ate 1.67-hydrate
title_short Tris(ethyl­enediamine)­nickel(II) 1H-pyrazole-3,5-dicarboxyl­ate 1.67-hydrate
title_sort tris(ethyl­enediamine)­nickel(ii) 1h-pyrazole-3,5-dicarboxyl­ate 1.67-hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007365/
https://www.ncbi.nlm.nih.gov/pubmed/21588159
http://dx.doi.org/10.1107/S1600536810027066
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