Bis(dimethyl sulfoxide)­hydridobis(triphenyl­phosphane)cobalt(I)

The title compound, [CoH(C(18)H(15)P)(2)(C(2)H(6)OS)(2)], was synthesized by the reaction of chloridotris(triphenyl­phosphane)cobalt(I), [ClCo(PPh(3))(3)], in the presence of one equivalent potassium hydridotris(pyrazol­yl)borate in dimethyl sulfoxide. The structure displays a distorted trigonal-pyr...

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Detalles Bibliográficos
Autores principales: Hapke, Marko, Weding, Nico, Spannenberg, Anke
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007366/
https://www.ncbi.nlm.nih.gov/pubmed/21588105
http://dx.doi.org/10.1107/S1600536810029466
Descripción
Sumario:The title compound, [CoH(C(18)H(15)P)(2)(C(2)H(6)OS)(2)], was synthesized by the reaction of chloridotris(triphenyl­phosphane)cobalt(I), [ClCo(PPh(3))(3)], in the presence of one equivalent potassium hydridotris(pyrazol­yl)borate in dimethyl sulfoxide. The structure displays a distorted trigonal-pyramidally coordinated cobalt(I) atom, with two phosphane ligands and one DMSO ligand in the equatorial plane. The coordination is completed by one further DMSO ligand and the anionic hydride in the axial positions.

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