Bis(dimethyl sulfoxide)­hydridobis(triphenyl­phosphane)cobalt(I)

The title compound, [CoH(C(18)H(15)P)(2)(C(2)H(6)OS)(2)], was synthesized by the reaction of chloridotris(triphenyl­phosphane)cobalt(I), [ClCo(PPh(3))(3)], in the presence of one equivalent potassium hydridotris(pyrazol­yl)borate in dimethyl sulfoxide. The structure displays a distorted trigonal-pyr...

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Detalles Bibliográficos
Autores principales: Hapke, Marko, Weding, Nico, Spannenberg, Anke
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007366/
https://www.ncbi.nlm.nih.gov/pubmed/21588105
http://dx.doi.org/10.1107/S1600536810029466
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author Hapke, Marko
Weding, Nico
Spannenberg, Anke
author_facet Hapke, Marko
Weding, Nico
Spannenberg, Anke
author_sort Hapke, Marko
collection PubMed
description The title compound, [CoH(C(18)H(15)P)(2)(C(2)H(6)OS)(2)], was synthesized by the reaction of chloridotris(triphenyl­phosphane)cobalt(I), [ClCo(PPh(3))(3)], in the presence of one equivalent potassium hydridotris(pyrazol­yl)borate in dimethyl sulfoxide. The structure displays a distorted trigonal-pyramidally coordinated cobalt(I) atom, with two phosphane ligands and one DMSO ligand in the equatorial plane. The coordination is completed by one further DMSO ligand and the anionic hydride in the axial positions.
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spelling pubmed-30073662010-12-30 Bis(dimethyl sulfoxide)­hydridobis(triphenyl­phosphane)cobalt(I) Hapke, Marko Weding, Nico Spannenberg, Anke Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CoH(C(18)H(15)P)(2)(C(2)H(6)OS)(2)], was synthesized by the reaction of chloridotris(triphenyl­phosphane)cobalt(I), [ClCo(PPh(3))(3)], in the presence of one equivalent potassium hydridotris(pyrazol­yl)borate in dimethyl sulfoxide. The structure displays a distorted trigonal-pyramidally coordinated cobalt(I) atom, with two phosphane ligands and one DMSO ligand in the equatorial plane. The coordination is completed by one further DMSO ligand and the anionic hydride in the axial positions. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007366/ /pubmed/21588105 http://dx.doi.org/10.1107/S1600536810029466 Text en © Hapke et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hapke, Marko
Weding, Nico
Spannenberg, Anke
Bis(dimethyl sulfoxide)­hydridobis(triphenyl­phosphane)cobalt(I)
title Bis(dimethyl sulfoxide)­hydridobis(triphenyl­phosphane)cobalt(I)
title_full Bis(dimethyl sulfoxide)­hydridobis(triphenyl­phosphane)cobalt(I)
title_fullStr Bis(dimethyl sulfoxide)­hydridobis(triphenyl­phosphane)cobalt(I)
title_full_unstemmed Bis(dimethyl sulfoxide)­hydridobis(triphenyl­phosphane)cobalt(I)
title_short Bis(dimethyl sulfoxide)­hydridobis(triphenyl­phosphane)cobalt(I)
title_sort bis(dimethyl sulfoxide)­hydridobis(triphenyl­phosphane)cobalt(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007366/
https://www.ncbi.nlm.nih.gov/pubmed/21588105
http://dx.doi.org/10.1107/S1600536810029466
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AT wedingnico bisdimethylsulfoxidehydridobistriphenylphosphanecobalti
AT spannenberganke bisdimethylsulfoxidehydridobistriphenylphosphanecobalti

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