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catena-Poly[[μ(3)-hydroxido-tetra-μ(2)-pyrid­azine-1:2κ(4) N:N′;1:3κ(2) N:N′;2:3κ(2) N:N′-tetrakis(selenocyanato)-1κN,2κN,3κ(2) N-trizinc(II)]-μ-cyanido-1:2′κ(2) C:N]

In the crystal structure of the title compound, [Zn(3)(NCSe)(4)(OH)(CN)(C(4)H(4)N(2))(4)](n) one of the two crystallograph­ically independent zinc(II) cations is coordinated by two terminal N-bonded seleno­cyanato anions and two N atoms of two symmetry-related pyridazine ligands in a trigonal-bipyra...

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Detalles Bibliográficos
Autores principales: Reinert, Thorben, Boeckmann, Jan, Jess, Inke, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007368/
https://www.ncbi.nlm.nih.gov/pubmed/21588094
http://dx.doi.org/10.1107/S1600536810029107
Descripción
Sumario:In the crystal structure of the title compound, [Zn(3)(NCSe)(4)(OH)(CN)(C(4)H(4)N(2))(4)](n) one of the two crystallograph­ically independent zinc(II) cations is coordinated by two terminal N-bonded seleno­cyanato anions and two N atoms of two symmetry-related pyridazine ligands in a trigonal-bipyramidal geometry, while the other zinc(II) cation is coordinated by one terminal N-bonded seleno­cyanato anion, one μ-1,2-cyanido anion and three N atoms of three crystallographically independent pyridazine ligands in a slightly distorted octa­hedral coordination geometry. The zinc(II) atoms are further connected via a μ(3)-hydroxido anion into trinuclear building blocks. The formula unit consists of three zinc cations, four seleno­cyanato anions, one μ(3)-hydroxido anion, four pyridazine mol­ecules as well as one cyanido anion. The asymmetric unit contains half of a formula unit. One of the zinc atoms, two seleno­cyanato anions, two pyridazine ligands and the μ(3)-hydroxido anion are located on a crystallographic mirror plane, whereas the cyanido anion is located on a twofold rotation axis. Therefore, this anion is disordered due to symmetry. The cyanido anions connect the metal centres into polymeric zigzag chains propagating along the a axis.