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catena-Poly[[μ(3)-hydroxido-tetra-μ(2)-pyrid­azine-1:2κ(4) N:N′;1:3κ(2) N:N′;2:3κ(2) N:N′-tetrakis(selenocyanato)-1κN,2κN,3κ(2) N-trizinc(II)]-μ-cyanido-1:2′κ(2) C:N]

In the crystal structure of the title compound, [Zn(3)(NCSe)(4)(OH)(CN)(C(4)H(4)N(2))(4)](n) one of the two crystallograph­ically independent zinc(II) cations is coordinated by two terminal N-bonded seleno­cyanato anions and two N atoms of two symmetry-related pyridazine ligands in a trigonal-bipyra...

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Detalles Bibliográficos
Autores principales: Reinert, Thorben, Boeckmann, Jan, Jess, Inke, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007368/
https://www.ncbi.nlm.nih.gov/pubmed/21588094
http://dx.doi.org/10.1107/S1600536810029107
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author Reinert, Thorben
Boeckmann, Jan
Jess, Inke
Näther, Christian
author_facet Reinert, Thorben
Boeckmann, Jan
Jess, Inke
Näther, Christian
author_sort Reinert, Thorben
collection PubMed
description In the crystal structure of the title compound, [Zn(3)(NCSe)(4)(OH)(CN)(C(4)H(4)N(2))(4)](n) one of the two crystallograph­ically independent zinc(II) cations is coordinated by two terminal N-bonded seleno­cyanato anions and two N atoms of two symmetry-related pyridazine ligands in a trigonal-bipyramidal geometry, while the other zinc(II) cation is coordinated by one terminal N-bonded seleno­cyanato anion, one μ-1,2-cyanido anion and three N atoms of three crystallographically independent pyridazine ligands in a slightly distorted octa­hedral coordination geometry. The zinc(II) atoms are further connected via a μ(3)-hydroxido anion into trinuclear building blocks. The formula unit consists of three zinc cations, four seleno­cyanato anions, one μ(3)-hydroxido anion, four pyridazine mol­ecules as well as one cyanido anion. The asymmetric unit contains half of a formula unit. One of the zinc atoms, two seleno­cyanato anions, two pyridazine ligands and the μ(3)-hydroxido anion are located on a crystallographic mirror plane, whereas the cyanido anion is located on a twofold rotation axis. Therefore, this anion is disordered due to symmetry. The cyanido anions connect the metal centres into polymeric zigzag chains propagating along the a axis.
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spelling pubmed-30073682010-12-30 catena-Poly[[μ(3)-hydroxido-tetra-μ(2)-pyrid­azine-1:2κ(4) N:N′;1:3κ(2) N:N′;2:3κ(2) N:N′-tetrakis(selenocyanato)-1κN,2κN,3κ(2) N-trizinc(II)]-μ-cyanido-1:2′κ(2) C:N] Reinert, Thorben Boeckmann, Jan Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Zn(3)(NCSe)(4)(OH)(CN)(C(4)H(4)N(2))(4)](n) one of the two crystallograph­ically independent zinc(II) cations is coordinated by two terminal N-bonded seleno­cyanato anions and two N atoms of two symmetry-related pyridazine ligands in a trigonal-bipyramidal geometry, while the other zinc(II) cation is coordinated by one terminal N-bonded seleno­cyanato anion, one μ-1,2-cyanido anion and three N atoms of three crystallographically independent pyridazine ligands in a slightly distorted octa­hedral coordination geometry. The zinc(II) atoms are further connected via a μ(3)-hydroxido anion into trinuclear building blocks. The formula unit consists of three zinc cations, four seleno­cyanato anions, one μ(3)-hydroxido anion, four pyridazine mol­ecules as well as one cyanido anion. The asymmetric unit contains half of a formula unit. One of the zinc atoms, two seleno­cyanato anions, two pyridazine ligands and the μ(3)-hydroxido anion are located on a crystallographic mirror plane, whereas the cyanido anion is located on a twofold rotation axis. Therefore, this anion is disordered due to symmetry. The cyanido anions connect the metal centres into polymeric zigzag chains propagating along the a axis. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007368/ /pubmed/21588094 http://dx.doi.org/10.1107/S1600536810029107 Text en © Reinert et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Reinert, Thorben
Boeckmann, Jan
Jess, Inke
Näther, Christian
catena-Poly[[μ(3)-hydroxido-tetra-μ(2)-pyrid­azine-1:2κ(4) N:N′;1:3κ(2) N:N′;2:3κ(2) N:N′-tetrakis(selenocyanato)-1κN,2κN,3κ(2) N-trizinc(II)]-μ-cyanido-1:2′κ(2) C:N]
title catena-Poly[[μ(3)-hydroxido-tetra-μ(2)-pyrid­azine-1:2κ(4) N:N′;1:3κ(2) N:N′;2:3κ(2) N:N′-tetrakis(selenocyanato)-1κN,2κN,3κ(2) N-trizinc(II)]-μ-cyanido-1:2′κ(2) C:N]
title_full catena-Poly[[μ(3)-hydroxido-tetra-μ(2)-pyrid­azine-1:2κ(4) N:N′;1:3κ(2) N:N′;2:3κ(2) N:N′-tetrakis(selenocyanato)-1κN,2κN,3κ(2) N-trizinc(II)]-μ-cyanido-1:2′κ(2) C:N]
title_fullStr catena-Poly[[μ(3)-hydroxido-tetra-μ(2)-pyrid­azine-1:2κ(4) N:N′;1:3κ(2) N:N′;2:3κ(2) N:N′-tetrakis(selenocyanato)-1κN,2κN,3κ(2) N-trizinc(II)]-μ-cyanido-1:2′κ(2) C:N]
title_full_unstemmed catena-Poly[[μ(3)-hydroxido-tetra-μ(2)-pyrid­azine-1:2κ(4) N:N′;1:3κ(2) N:N′;2:3κ(2) N:N′-tetrakis(selenocyanato)-1κN,2κN,3κ(2) N-trizinc(II)]-μ-cyanido-1:2′κ(2) C:N]
title_short catena-Poly[[μ(3)-hydroxido-tetra-μ(2)-pyrid­azine-1:2κ(4) N:N′;1:3κ(2) N:N′;2:3κ(2) N:N′-tetrakis(selenocyanato)-1κN,2κN,3κ(2) N-trizinc(II)]-μ-cyanido-1:2′κ(2) C:N]
title_sort catena-poly[[μ(3)-hydroxido-tetra-μ(2)-pyrid­azine-1:2κ(4) n:n′;1:3κ(2) n:n′;2:3κ(2) n:n′-tetrakis(selenocyanato)-1κn,2κn,3κ(2) n-trizinc(ii)]-μ-cyanido-1:2′κ(2) c:n]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007368/
https://www.ncbi.nlm.nih.gov/pubmed/21588094
http://dx.doi.org/10.1107/S1600536810029107
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