Methyl 1-{4-[(S)-2-(meth­oxy­carbon­yl)pyrrolidin-1-yl]-3,6-dioxocyclo­hexa-1,4-dien-1-yl}pyrrolidine-2-carboxyl­ate

The complete mol­ecule of the title diproline ester quinone, C(18)H(22)N(2)O(6), is generated by a crystallographic twofold axis, which passes through the centre of the benzene ring. Both –CO(2)Me groups are orientated to the same side of the benzene ring, with the carbonyl groups pointing roughly t...

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Detalles Bibliográficos
Autores principales: Garden, Simon J., Skakle, Janet M. S., Tiekink, Edward R. T., Wardell, James L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007373/
https://www.ncbi.nlm.nih.gov/pubmed/21588372
http://dx.doi.org/10.1107/S1600536810027947
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author Garden, Simon J.
Skakle, Janet M. S.
Tiekink, Edward R. T.
Wardell, James L.
author_facet Garden, Simon J.
Skakle, Janet M. S.
Tiekink, Edward R. T.
Wardell, James L.
author_sort Garden, Simon J.
collection PubMed
description The complete mol­ecule of the title diproline ester quinone, C(18)H(22)N(2)O(6), is generated by a crystallographic twofold axis, which passes through the centre of the benzene ring. Both –CO(2)Me groups are orientated to the same side of the benzene ring, with the carbonyl groups pointing roughly towards each other. The conformation of the proline residue is an envelope. In the crystal, a three-dimensional network is sustained by C—H⋯O inter­actions involving both the quinone and carbonyl O atoms.
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spelling pubmed-30073732010-12-30 Methyl 1-{4-[(S)-2-(meth­oxy­carbon­yl)pyrrolidin-1-yl]-3,6-dioxocyclo­hexa-1,4-dien-1-yl}pyrrolidine-2-carboxyl­ate Garden, Simon J. Skakle, Janet M. S. Tiekink, Edward R. T. Wardell, James L. Acta Crystallogr Sect E Struct Rep Online Organic Papers The complete mol­ecule of the title diproline ester quinone, C(18)H(22)N(2)O(6), is generated by a crystallographic twofold axis, which passes through the centre of the benzene ring. Both –CO(2)Me groups are orientated to the same side of the benzene ring, with the carbonyl groups pointing roughly towards each other. The conformation of the proline residue is an envelope. In the crystal, a three-dimensional network is sustained by C—H⋯O inter­actions involving both the quinone and carbonyl O atoms. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007373/ /pubmed/21588372 http://dx.doi.org/10.1107/S1600536810027947 Text en © Garden et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Garden, Simon J.
Skakle, Janet M. S.
Tiekink, Edward R. T.
Wardell, James L.
Methyl 1-{4-[(S)-2-(meth­oxy­carbon­yl)pyrrolidin-1-yl]-3,6-dioxocyclo­hexa-1,4-dien-1-yl}pyrrolidine-2-carboxyl­ate
title Methyl 1-{4-[(S)-2-(meth­oxy­carbon­yl)pyrrolidin-1-yl]-3,6-dioxocyclo­hexa-1,4-dien-1-yl}pyrrolidine-2-carboxyl­ate
title_full Methyl 1-{4-[(S)-2-(meth­oxy­carbon­yl)pyrrolidin-1-yl]-3,6-dioxocyclo­hexa-1,4-dien-1-yl}pyrrolidine-2-carboxyl­ate
title_fullStr Methyl 1-{4-[(S)-2-(meth­oxy­carbon­yl)pyrrolidin-1-yl]-3,6-dioxocyclo­hexa-1,4-dien-1-yl}pyrrolidine-2-carboxyl­ate
title_full_unstemmed Methyl 1-{4-[(S)-2-(meth­oxy­carbon­yl)pyrrolidin-1-yl]-3,6-dioxocyclo­hexa-1,4-dien-1-yl}pyrrolidine-2-carboxyl­ate
title_short Methyl 1-{4-[(S)-2-(meth­oxy­carbon­yl)pyrrolidin-1-yl]-3,6-dioxocyclo­hexa-1,4-dien-1-yl}pyrrolidine-2-carboxyl­ate
title_sort methyl 1-{4-[(s)-2-(meth­oxy­carbon­yl)pyrrolidin-1-yl]-3,6-dioxocyclo­hexa-1,4-dien-1-yl}pyrrolidine-2-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007373/
https://www.ncbi.nlm.nih.gov/pubmed/21588372
http://dx.doi.org/10.1107/S1600536810027947
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AT tiekinkedwardrt methyl14s2methoxycarbonylpyrrolidin1yl36dioxocyclohexa14dien1ylpyrrolidine2carboxylate
AT wardelljamesl methyl14s2methoxycarbonylpyrrolidin1yl36dioxocyclohexa14dien1ylpyrrolidine2carboxylate

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