Cargando…

(E)-1-(4-Amino­phen­yl)-3-(2,4,5-trimeth­oxy­phen­yl)prop-2-en-1-one

Mol­ecules of the title amino­chalcone, C(18)H(19)NO(4), are twisted, with a dihedral angle of 11.26 (6)° between the 4-amino­phenyl and 2,4,5-trimeth­oxy­phenyl rings. The conformations of the three meth­oxy groups with respect to the benzene ring are slightly different. Two meth­oxy groups are alm...

Descripción completa

Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kobkeatthawin, Thawanrat, Ruanwas, Pumsak, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007376/
https://www.ncbi.nlm.nih.gov/pubmed/21588292
http://dx.doi.org/10.1107/S1600536810026346
_version_ 1782194341976997888
author Fun, Hoong-Kun
Kobkeatthawin, Thawanrat
Ruanwas, Pumsak
Chantrapromma, Suchada
author_facet Fun, Hoong-Kun
Kobkeatthawin, Thawanrat
Ruanwas, Pumsak
Chantrapromma, Suchada
author_sort Fun, Hoong-Kun
collection PubMed
description Mol­ecules of the title amino­chalcone, C(18)H(19)NO(4), are twisted, with a dihedral angle of 11.26 (6)° between the 4-amino­phenyl and 2,4,5-trimeth­oxy­phenyl rings. The conformations of the three meth­oxy groups with respect to the benzene ring are slightly different. Two meth­oxy groups are almost coplanar with the attached benzene ring [C—O—C—C torsion angles of −1.45 (19) and 1.5 (2)°], while the third is (−)-synclinal with the attached benzene ring [C—O—C—C = −81.36 (17)°]. In the crystal structure, mol­ecules are stacked into columns along the b axis and mol­ecules in adjacent columns are linked by N—H⋯O hydrogen bonds into V-shaped double columns. Weak π–π inter­actions are also observed, with a centroid-centroid distance of 3.7532 (8) Å.
format Text
id pubmed-3007376
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30073762010-12-30 (E)-1-(4-Amino­phen­yl)-3-(2,4,5-trimeth­oxy­phen­yl)prop-2-en-1-one Fun, Hoong-Kun Kobkeatthawin, Thawanrat Ruanwas, Pumsak Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers Mol­ecules of the title amino­chalcone, C(18)H(19)NO(4), are twisted, with a dihedral angle of 11.26 (6)° between the 4-amino­phenyl and 2,4,5-trimeth­oxy­phenyl rings. The conformations of the three meth­oxy groups with respect to the benzene ring are slightly different. Two meth­oxy groups are almost coplanar with the attached benzene ring [C—O—C—C torsion angles of −1.45 (19) and 1.5 (2)°], while the third is (−)-synclinal with the attached benzene ring [C—O—C—C = −81.36 (17)°]. In the crystal structure, mol­ecules are stacked into columns along the b axis and mol­ecules in adjacent columns are linked by N—H⋯O hydrogen bonds into V-shaped double columns. Weak π–π inter­actions are also observed, with a centroid-centroid distance of 3.7532 (8) Å. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007376/ /pubmed/21588292 http://dx.doi.org/10.1107/S1600536810026346 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Kobkeatthawin, Thawanrat
Ruanwas, Pumsak
Chantrapromma, Suchada
(E)-1-(4-Amino­phen­yl)-3-(2,4,5-trimeth­oxy­phen­yl)prop-2-en-1-one
title (E)-1-(4-Amino­phen­yl)-3-(2,4,5-trimeth­oxy­phen­yl)prop-2-en-1-one
title_full (E)-1-(4-Amino­phen­yl)-3-(2,4,5-trimeth­oxy­phen­yl)prop-2-en-1-one
title_fullStr (E)-1-(4-Amino­phen­yl)-3-(2,4,5-trimeth­oxy­phen­yl)prop-2-en-1-one
title_full_unstemmed (E)-1-(4-Amino­phen­yl)-3-(2,4,5-trimeth­oxy­phen­yl)prop-2-en-1-one
title_short (E)-1-(4-Amino­phen­yl)-3-(2,4,5-trimeth­oxy­phen­yl)prop-2-en-1-one
title_sort (e)-1-(4-amino­phen­yl)-3-(2,4,5-trimeth­oxy­phen­yl)prop-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007376/
https://www.ncbi.nlm.nih.gov/pubmed/21588292
http://dx.doi.org/10.1107/S1600536810026346
work_keys_str_mv AT funhoongkun e14aminophenyl3245trimethoxyphenylprop2en1one
AT kobkeatthawinthawanrat e14aminophenyl3245trimethoxyphenylprop2en1one
AT ruanwaspumsak e14aminophenyl3245trimethoxyphenylprop2en1one
AT chantraprommasuchada e14aminophenyl3245trimethoxyphenylprop2en1one