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(E)-1-(4-Aminophenyl)-3-(2,4,5-trimethoxyphenyl)prop-2-en-1-one
Molecules of the title aminochalcone, C(18)H(19)NO(4), are twisted, with a dihedral angle of 11.26 (6)° between the 4-aminophenyl and 2,4,5-trimethoxyphenyl rings. The conformations of the three methoxy groups with respect to the benzene ring are slightly different. Two methoxy groups are alm...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007376/ https://www.ncbi.nlm.nih.gov/pubmed/21588292 http://dx.doi.org/10.1107/S1600536810026346 |
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author | Fun, Hoong-Kun Kobkeatthawin, Thawanrat Ruanwas, Pumsak Chantrapromma, Suchada |
author_facet | Fun, Hoong-Kun Kobkeatthawin, Thawanrat Ruanwas, Pumsak Chantrapromma, Suchada |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | Molecules of the title aminochalcone, C(18)H(19)NO(4), are twisted, with a dihedral angle of 11.26 (6)° between the 4-aminophenyl and 2,4,5-trimethoxyphenyl rings. The conformations of the three methoxy groups with respect to the benzene ring are slightly different. Two methoxy groups are almost coplanar with the attached benzene ring [C—O—C—C torsion angles of −1.45 (19) and 1.5 (2)°], while the third is (−)-synclinal with the attached benzene ring [C—O—C—C = −81.36 (17)°]. In the crystal structure, molecules are stacked into columns along the b axis and molecules in adjacent columns are linked by N—H⋯O hydrogen bonds into V-shaped double columns. Weak π–π interactions are also observed, with a centroid-centroid distance of 3.7532 (8) Å. |
format | Text |
id | pubmed-3007376 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30073762010-12-30 (E)-1-(4-Aminophenyl)-3-(2,4,5-trimethoxyphenyl)prop-2-en-1-one Fun, Hoong-Kun Kobkeatthawin, Thawanrat Ruanwas, Pumsak Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers Molecules of the title aminochalcone, C(18)H(19)NO(4), are twisted, with a dihedral angle of 11.26 (6)° between the 4-aminophenyl and 2,4,5-trimethoxyphenyl rings. The conformations of the three methoxy groups with respect to the benzene ring are slightly different. Two methoxy groups are almost coplanar with the attached benzene ring [C—O—C—C torsion angles of −1.45 (19) and 1.5 (2)°], while the third is (−)-synclinal with the attached benzene ring [C—O—C—C = −81.36 (17)°]. In the crystal structure, molecules are stacked into columns along the b axis and molecules in adjacent columns are linked by N—H⋯O hydrogen bonds into V-shaped double columns. Weak π–π interactions are also observed, with a centroid-centroid distance of 3.7532 (8) Å. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007376/ /pubmed/21588292 http://dx.doi.org/10.1107/S1600536810026346 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Kobkeatthawin, Thawanrat Ruanwas, Pumsak Chantrapromma, Suchada (E)-1-(4-Aminophenyl)-3-(2,4,5-trimethoxyphenyl)prop-2-en-1-one |
title | (E)-1-(4-Aminophenyl)-3-(2,4,5-trimethoxyphenyl)prop-2-en-1-one |
title_full | (E)-1-(4-Aminophenyl)-3-(2,4,5-trimethoxyphenyl)prop-2-en-1-one |
title_fullStr | (E)-1-(4-Aminophenyl)-3-(2,4,5-trimethoxyphenyl)prop-2-en-1-one |
title_full_unstemmed | (E)-1-(4-Aminophenyl)-3-(2,4,5-trimethoxyphenyl)prop-2-en-1-one |
title_short | (E)-1-(4-Aminophenyl)-3-(2,4,5-trimethoxyphenyl)prop-2-en-1-one |
title_sort | (e)-1-(4-aminophenyl)-3-(2,4,5-trimethoxyphenyl)prop-2-en-1-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007376/ https://www.ncbi.nlm.nih.gov/pubmed/21588292 http://dx.doi.org/10.1107/S1600536810026346 |
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