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Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate)
In the title trichodermin compound (systematic name: 12,13-epoxytrichothec-9-en-4β-yl 4-fluorobenzoate), C(22)H(25)FO(4), the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the different conformations, viz. chair and half-chair. As for the seven-memb...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007378/ https://www.ncbi.nlm.nih.gov/pubmed/21588390 http://dx.doi.org/10.1107/S1600536810028461 |
| Sumario: | In the title trichodermin compound (systematic name: 12,13-epoxytrichothec-9-en-4β-yl 4-fluorobenzoate), C(22)H(25)FO(4), the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the different conformations, viz. chair and half-chair. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 68.67 (2)°; these two mean planes are nearly perpendicular to the epoxy ring with angles of 87.97 (2)and 88.14 (2)°, respectively. |
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